본문 바로가기
HOME> 논문 > 논문 검색상세

논문 상세정보

Preparation of Azides from Hydrazines by using Dinitrogen Tetroxide as Nitrosonium Ion Source

Kim, Kweon    (Department of Chemistry, Korea Advanced Institute of Science and Technology   ); Kim, Yong-Hae    (Department of Chemistry, Korea Advanced Institute of Science and Technology  );
  • 초록

    Various hydrazines such as aryl-, carbonyl-, and sulfonyl-hydrazine were reacted with dinitrogen tetroxide to give the corresponding azides in excellent yields under mild ocnditions at low temperature $(-20-40^\circ{C)}$ in acetonitrile. The reaction appears to be initiated by formation of the .betha.-nitroso hydrazine intermediate which converts into the azide product.


  • 주제어

    Dinitrogen tetroxide .   Nitrosation .   Hydrazine .   Hydrazide .   Azide .   Nitrosoniumion.  

 저자의 다른 논문

  • Kim, Yong-Hae (11)

    1. 1981 "Direct Oxidation of Benzimidazole-2-thiol to the Benzimidazole-2-sulfonic Acid with Superoxide Ion" Bulletin of the Korean Chemical Society 2 (3): 122~123    
    2. 1983 "S-Transmethylation on Sulfur of Heterocycles with S-Methylmethioninemethyl Ester Iodide" Bulletin of the Korean Chemical Society 4 (3): 151~152    
    3. 1984 "Toxicity and Biological Activity of Extracts from Stichopus japonicus" Archives of pharmacal research : a publication of the Pharmaceutical Society of Korea 7 (1): 61~62    
    4. 1984 "Novel Dechlorination of Arylsulfenyl Chlorides with Superoxide Anion (O$_2^-$)" Bulletin of the Korean Chemical Society 5 (6): 266~268    
    5. 1985 "Unusually Stable Thiolsulfinate: o-Hydroxyphenyl-o-hydroxybenzene-thiolsulfinate" Bulletin of the Korean Chemical Society 6 (6): 381~382    
    6. 1987 "Characterization of 2-Aminodihydropyrimidines" Bulletin of the Korean Chemical Society 8 (1): 53~55    
    7. 1987 "Desulfurization of Thioamide Derivatives into Their Corresponding Amides Using Superoxide Anion (O$_2^-$)" Bulletin of the Korean Chemical Society 8 (1): 56~58    
    8. 1988 "Synthesis of Acyclic Nucleosides of 2-Thio-Pyrimidines and -Purines Using a New Coupling Agent of Lithium Bromide" Bulletin of the Korean Chemical Society 9 (5): 295~298    
    9. 1993 "Facile Synthesis of Multiple Ketones from $\alpha$-Oximinoketones Using Dinitrogen Tetroxide" Bulletin of the Korean Chemical Society 14 (6): 649~650    
    10. 1998 "DK1002에 대한 급성독성시험 및 유전독성에 관한 연구" Journal of toxicology and public health : an official journal of the Korean Society of Toxicology 14 (3): 427~433    

 활용도 분석

  • 상세보기

    amChart 영역
  • 원문보기

    amChart 영역

원문보기

무료다운로드
유료다운로드

유료 다운로드의 경우 해당 사이트의 정책에 따라 신규 회원가입, 로그인, 유료 구매 등이 필요할 수 있습니다. 해당 사이트에서 발생하는 귀하의 모든 정보활동은 NDSL의 서비스 정책과 무관합니다.

원문복사신청을 하시면, 일부 해외 인쇄학술지의 경우 외국학술지지원센터(FRIC)에서
무료 원문복사 서비스를 제공합니다.

NDSL에서는 해당 원문을 복사서비스하고 있습니다. 위의 원문복사신청 또는 장바구니 담기를 통하여 원문복사서비스 이용이 가능합니다.

이 논문과 함께 출판된 논문 + 더보기