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유성오염의 세척성에 관한 연구(제1보) -개체유성오염의 세척성-
Studies on the Detergency of Oily Soils (Part 1) - Detergency of Soild Oily Soils -

김영희    (부산대학교 가정대학 의류학과   ); 정두진    (부산대학교 가정대학 의류학과  );
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    The interaction and detergency between oily soil and surfactant solution were studied Samples used were tristearin, tripalmitin and their mixture as a triglyceride, myristic acid as a fatty acid and sodium dodecyl sulfate (SDS) as surfactant. The results were as follows: 1. The mixtures of model oily soils were formed of eutectic point and their melting point were lower than them of individual oily soils. 2. The formation of liquid crystalline (LC) phase was recognized in the triangle phase diagram for SDS~ water~model oily soil system. The areas of LC phase region were in the order of SHS~ water~myristir acid> SDS~ water~mixture of tristearin, tripalmitin and myristic acid (TS/TP/M)>SDS~water~mixture of tristearin and tripalmitin (TS/TP) 3. The LC phase region expanded to wide concentration range of SDS solution and high concentration range of model oily soil with increasing temperature. Particularity, the LC phase region expanded highly at $30~40^{\circ}C$ but when the temperature was elevated above $40^{\circ}C$ , expanding tendency decreased. 4. In the system of myristic acid and TS/TP/M contacted with SDS solution, the LC phase was already formed at $28^{\circ}C$ and the region of the LC phase were expanded with increasing temperature. But in the system of TS/TP contacted with SDS solution, the LC phase was not formed in whole experiment temperature. 5. The detergency of myristic acid was very high ann it was recognized that the formation of the LC phase played an important role in the detergency. The detergency of TS/TP was very for low, but when TS/TF was mixed with myristic acid, the detergency of TS/TP increased. It is supposed that the LC phase was formed butween SDS solution and myristic acid promoted to penetration of SDS solution into the inner parts of TS/TP.


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  • 김영희 (4)

    1. 1993 "점토(粘土)와 염색(染色)한 올레산(酸)을 모델오염(汚染)으로 한 인공오염포(人工汚染布)의 제작(製作)과 그 세척성(洗滌性)에 관(關)한 연구(硏究)" 한국의류학회지 = Journal of the Korean Society of Clothing and Textiles 17 (2): 233~245    
    2. 1995 "유성오염의 세척성에 관한 연구(제2보) -유화와 롤링업에 의한 액체유성오염의 세척성-" 한국의류학회지 = Journal of the Korean Society of Clothing and Textiles 19 (2): 356~365    
    3. 1995 "유성오염의 세척성에 관한 연구(제3보) -액수형성에 의한 액체유성오염의 세척성-" 한국의류학회지 = Journal of the Korean Society of Clothing and Textiles 19 (3): 426~433    
  • 정두진 (9)

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