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大氣保全 : 韓國大氣保全學會誌 v.12 no.2, 1996년, pp.199 - 209   피인용횟수: 4

DNPH 카트리지와 HPLC를 이용한 대기 중 카르보닐화합물의 농도측정
Measurement of Carbonyl Compounds in Ambient Air using a DNPH Cartridge coupled with HPLC Method

황윤정    (영남대학교 환경공학과   ); 박상곤    (대전전문대학 환경관리과   ); 백성옥    (영남대학교 환경공학과  );
  • 초록

    The purpose of this study is to evaluate analytical method for the measurement of carbonyl compounds and to apply method to the measurement of indoor and outdoor concentrations of these compounds at public facilities. For sampling, 2.4-dinitrophenylhydrazine (DNPH) coated DNPH-Silica cartridges were uwed in this study. DNPH reacts with carbonyl compounds and forms carbonyl hydrazone, The carbonyl hydarzone was eluted from the cartridge with acetonitrile and analyzed by reverse-phase HPLC with UV detection. Possible interference caused by ozone during sampling was eliminated by using KI trap commected in series with the DNPH-Silica cartridge. A number of experimental studies were undertaken to evaluate and validate the analytical method, including collection efficiency, recovery, repeatability, lower limits of detection, and effect of ozone. Indoor and outdoor measurements of carbonyl compounds were simultaneously carried out at 14 public facilities located in Taegu city and Kyungsan city from June to July, 1995. Except for one or two sites, the indoor concentrations were found to be higher than the outdoor concentrations for carbonyl compounds. And the concentrations of carbonyl compounds measured in the morning and afternoon were showed higher than the concentrations measured in the evening.

  • 참고문헌 (25)

    1. Analysis of aldehydes in cloud and fogwater samples by HPLC with a postcolumn reaction detector , Igawa,M.;J.W.Munger;M.R.Hoffmann , Environ. Sci. Technol / v.23,pp.556-561,
    2. Monitoring of parts-per billion levels of formaldehyde using a diffusive sampler , Levin,J.O.;R.Lindahl;K.Aadersson , JAPCA / v.39,pp.44-47,
    3. Photomchemical formations of lower aldehydes and lower fatty acids under long-range transport in central Japan , Satsumabayashi,H.;H.Kurita;Y.S.Chang;G.R.Carmichael , Atmospheric Environment / v.29,pp.255-266,
    4. Temperature dependence of the modified pararosanilne method for the determination of formaldehyde in air , Georghiou,P.E.;L.Harlick;L.Winsor;D.Snow , Analy. Chem / v.55,pp.567-570,
    5. Seasonal variations in ambient atmospheric levels of formaldehyde and acetaldehyde , Tanner,R.L.;Z.Meng , Environ. Sci. Technol / v.18,pp.723-726,
    6. Determination of volatile carbonyl compounds in clean air , Slemr,J. , Fresenius J. Anal. Chem / v.340,pp.672-677,
    7. Determination of formaldehyde by HPLC as the DNPH derivative following high-volume air sampling onto bisulfite-coated cellulose filters , Andrade,J.B.;R.L.Tanner , Atmospheric Environment / v.26A,pp.819-825,
    8. Visual colorimetric formaldehyde screening analysis for indoor air , Matthews,T.G.;T.C.Howell , JAPCA / v.31,pp.1181-1184,
    9. Formaldehyde measurements in dutch houses. schools and offices in the years 1977-1980 , Vanderwal,J.F. , Atmospheric Environment / v.16,pp.2471-2478,
    10. Destruction of formaldehyde with dielectric barrier discharge plasmas , Chang,M.B.;C.C.Lee , Environ. Sci. Technol / v.29,pp.181-186,
    11. Characteristics of aldehydes: Concentrations, sources, and exposures for indoor and outdoor residential microenvironments , Zhang,J.;Q.He;P.J.Lioy , Environ. Sci. Technol / v.28,pp.146-152,
    12. Vairavamurthy,A.;J.M.Roberts;L.Newman;E.D.Winegar(ed.);Keith,L.H.(ed.) , Sampling of atmospheric carbonyl compounds for determination by liquid chromatography after 2,4-dinitrophenylhydrazine labeling, sampling and analysis of airborne pollutants / v.,pp.150-151,
    13. A passive sampler for airborne formaldehyde , Grosjean,D.;E.L.WilliamsⅡ , Atmospheric Environment / v.26A,pp.2923-2928,
    14. Method TO11 : Determination of formaldehyde in ambient air using adsorbent cartridge followed by high performance liquid chromatography (HPLC), methods for termination of toxic organic compounds in air-EPA method , Winberry,Jr.;W.T.;N.T.Murphy;R.M.Riggan;Winberry,Jr.;W.T.;N.T.Murphy;R.M.Riggan , Noyes Data Corporation / v.,pp.294-331,
    15. Laboratory and field investigation of the DNPH cartridge technique for the measurement of atmospheric carbonyl compounds , Sirju,A.P.;P.B.Shepson , Environ. Sci. Technol / v.29,pp.384-392,
    16. Formaldehyde, methanol and hydrocarbon emissions from methanol-fueled cars , Williams,R.L.;F.Lipari;R.A.Potter , J. Air Waste Manage. Assoc / v.40,pp.747-756,
    17. Analysis of the change in atmospheric urban formaldehyde and photochemistry activity as a result of using methyl-t-butyl-ether (MTBE) as an additive in gasolines of the metropolitan area of mexico City , Humberto,B.A.;C.C.Rosaura;R.O.R.Guadalupe;S.E.Rodolfo;T.J.Ricardo , Atmospheric Environment / v.25B,pp.285-288,
    18. 2,4-Dinitrophenylhydrazine-coated silica gel cartridge method for determination of formaldehyde in air : Identification of an ozone Interference , Arnts,R.R.;S.B.Tejada , Environ. Sci. Technol / v.23,pp.1428-1430,
    19. Production of aldehydes as primary emissons and from secondary atmospheric reactions of alkenes and alkanes during the night and early morning hours , Altshuller,A.P. , Atmospheric Environment / v.27A,pp.21-32,
    20. 대기오염, 소음, 진동 공정시험방법 , 환경처 , 환경처 고시 제91-73호 / v.,pp.267-270,
    21. Determination of nanogram amounts of carbonyl as 2, 4-dinitrophenylhydrazones by high performance liquid chromatography , Fung,K.;D.Grosjean , Anal. Chem / v.53,pp.168-171,
    22. Ambient levels of formaldehyde and acetaldehyde in Atlanta, Georgia , Grosjean,E.;E.L.WilliamsⅡ;D.Grosjean , J. Air Waste Manage. Assoc / v.43,pp.469-474,
    23. 액체 크로마토그래프법에 의한 대기시료중 미량 알데히드류의 정량 , 이용근;정태우 , 한국대기보전학회지 / v.11,pp.339-349,
    24. Ambient levels of formaldehyde, acetaldehyde, and formic acid in southern California : Results of a one-year base-line study , Grosjean,D. , Environ. Sci. Technol / v.25,pp.710-715,
    25. Laboratory tests of KI and alkaline annular denuders , Parmar,S.S.;D.Grosjean , Atmospheric Environment / v.24A,pp.2695-2698,
  • 이 논문을 인용한 문헌 (4)

    1. 1997. "Variations of Concentration Levels of Volatile Organic Compounds in the Indoor Air due to Floor Waxing" 大氣保全 : 韓國大氣保全學會誌, 13(3): 221~229     
    2. Hwang, Yun-Jeong ; Park, Sang-Gon ; Baek, Seong-Ok 1998. "Comparison of Chromotropic Acid Method and DNPH-HPLC Method for the Measurement of Formaldehyde in the Air" 大氣保全 : 韓國大氣保全學會誌, 14(5): 519~524     
    3. 2000. "Contribution of Primary and Secondary Sources to the Atmospheric Concentrations of Carbonayl Compounds in Seoul" 한국대기환경학회지 = Journal of Korean Society for Atmospheric Environment, 16(4): 317~326     
    4. 2002. "Characteristics of Seasonal Source for Formaldehyde and Acetaldehyde in Metropolitan Areas" 한국대기환경학회지 = Journal of Korean Society for Atmospheric Environment, 18(1): 11~23     

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