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멤브레인 = Membrane Journal v.12 no.3, 2002년, pp.121 - 142   피인용횟수: 7

온실기체 분리회수를 위한 막분리기술 연구 동향
Research Trend of Membrane Technology for Separation of Carbon Dioxide from Flue Gas

김정훈   (한국화학연구원, 계면공학연구팀  ); 임지원   (한남대학교 공대 화학공학과UU0001481  ); 이수복   (한국화학연구원, 계면공학연구팀  );
  • 초록

    본 총설에서는 지구온실기체인 배가스내의 이산화탄소의 분리기술중 가장 잠재성이 큰 막분리기술에 관해 기술하였다. 고분자막에 대한 기체투과(용해확산)이론과 이산화탄소/질소의 물리적인 특성을 배경으로, 많은 문헌에서 발표된 고분자소재의 투과데이터를 분석하고 이를 통해 고분자막의 물리화학적인 구조와 이산화탄소/질소의 투과선택성의 상관관계를 설명하였다. 상업적으로 기체분리에 가장 널리 사용되는 중공사막모듈의 및 분리막공정의 동향에 대해 소개하였다. 마지막으로 국내외에서 발표된 이산화탄소/질소 분리막에 대한 현재까지의 연구동향과 앞으로의 전망에 대해 기술하였다.


    The $CO_2$ emission is the largest contribute for the green house effect. Among the existing chemical separation processes, the membrane separation technology is(/will be) the most potential process for $CO_2$ , separation from flue gas. Based on the solution-diffusion theory and physical properties of carbon dioxide/nitrogen and the permeation data in the literature, the relationships between physico-chemical structures of polymeric membrane materials and the perm-selectivities for $CO_2$ / $N_2$ gases were described in detail. The progress of membrane module and process development was introduced briefly. Finally, the worldwide research activity including South Korea's for carbon dioxide separation by membrane technology were introduced through the survey of papers and technical reports published.


  • 주제어

    $CO_2$ separation .   flue gas .   polymer membranes.  

  • 참고문헌 (76)

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  • 이 논문을 인용한 문헌 (7)

    1. 2003. "Permeation Behavior of Olefin/Nitrogen Gases through Siloxane based Polymeric Membranes" 멤브레인 = Membrane Journal, 13(4): 246~256     
    2. Lee, Hyung-Keun ; Kim, Dae-Hoon ; An, Young-Mo ; Jo, Hang-Dae ; Park, Jong-Soo 2009. "Studies on the $N_2/SF_6$ Permeation Behaviors Using the Polyethersulfone Hollow Fiber Membranes" 멤브레인 = Membrane Journal, 19(3): 244~251     
    3. Kim, Dae-Hoon ; Kim, Guang-Lim ; Jo, Hang-Dae ; Park, Jong-Soo ; Lee, Hyung-Keun 2010. "Study on the Separation of N2/SF6 Mixture Gas Using Polyimide Hollow Fiber Membrane" Korean chemical engineering research = 화학공학, 48(5): 660~667     
    4. Lee, Hyun-Jung ; Lee, Min-Woo ; Lee, Hyun-Kyung ; Lee, Sang-Hyup 2010. "Permeation and Permselectivity variation of $O_2$, $CF_4$ and $SF_6$ through Polymeric Hollow Fiber Membranes" 멤브레인 = Membrane Journal, 20(3): 249~258     
    5. Lee, Hyun-Jung ; Lee, Min-Woo ; Lee, Hyun-Kyung ; Choi, Ho-Sang ; Lee, Sang-Hyup 2011. "Recovery of $SF_6$ gas from Gaseous Mixture ($SF_6/N_2/O_2/CF_4$) through Polymeric Membranes" 멤브레인 = Membrane Journal, 21(1): 22~29     
    6. Lee, Hyun-Jung ; Lee, Hyun-Kyung ; Choi, Ho-Sang ; Lee, Sang-Hyup 2011. "Recovery of $SF_6$ from Gas Mixtures with Low Concentration of $SF_6$" 멤브레인 = Membrane Journal, 21(3): 256~262     
    7. Lee, Hyun-Jung ; Lee, Min-Woo ; Lee, Hyun-Kyung ; Lee, Sang-Hyup 2011. "Separation and Recovery of $SF_6$ Gas from $N_2/SF_6$ Gas Mixtures by using a Polymer Hollow Fiber Membranes" 대한환경공학회지 = Journal of Korean Society of Environmental Engineers, 33(1): 47~53     

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