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펄프 종이기술 = Journal of Korea Technical Association of the Pulp and Paper Industry v.36 no.5 = no.108, 2004년, pp.53 - 61  
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Properties and Biodegradability of Polylactide for Paper Coating Application - $Poly(_{L} -lactide)\;and\;Poly(_{D}-lactide)$ Blend -

Lim Hyun A    (Institute of Agricultural Science & Technology, Chonbuk National University   ); Kang Jin Ha    (Division of Forest Science, College of Agriculture and Life Sciences, Chonbuk National Univeristy  );
  • 초록

    [ $Poly(_{D}-ldactide)\;(_{D}-PLA)$ ] was synthesized to have low molecular weight for miscible blends with a high molecular $poly(_{L}-lactide)\;(_{L} -PLA)$ . The blends were prepared by dissolving the two components of $_{L}-PLA\;and\;_{D}-PLA\;(w/w)$ in chloroform (l00/0, 90/10, 70/30, 50/50, 30/70, 0/100). The miscibility of these miscible blends was characterized by gel-permeation chromatography (GPC), differential scanning calorimetry (DSC), and the selective degradability by enzymes (proteinase K, subtilisin and $\alpha$ -chymotrypsin). The coating efficiency of PLA blends onto paper was determined and the degrading activity cellulases by on these blends. The miscibility, coating efficiency and enzymatic degradability of these blends were decreased according to increasing of $_{D}-PLA$ blending part. Such results were attributed to the extent of coating application of PLA, with better miscibility (compatibility), coating efficiency and degradability due to a higher $_{L}-PLA$ content.


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