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Bulletin of the Korean Chemical Society v.26 no.2, 2005년, pp.292 - 296   피인용횟수: 1

Studies on the Properties of Thexylboronic Acid and Its Derivatives

Cha, Jin-Soon    (Department of Chemistry, Yeungnam University   ); Brown, Herbert C.    (The H. C. Brown & R. B. Wetherill Laboratories of Chemistry, Purdue University  );
  • 초록

    Physical and chemical properties of thexylboronic acid and its derivatives such as thexylboroxine and ethylene glycol or diethanolamine thexylboronic ester have been studied. Thexylboronic acid can be extracted from an organic solution with an aqueous sodium hydroxide solution as an “te”complex. It is readily converted into thexylboroxine in the presence of anhydrous magnesium sulfate in pentane. It reacts with simple alcohols only slowly; however, it reacts readily with excess diethanolamine in the presence of anhydrous magnesium sulfate to give the corresponding ester.


  • 주제어

    Property of thexylboronic acid .   Thexylboroxine .   Thexylboronic ester.  

  • 참고문헌 (39)

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  • 이 논문을 인용한 문헌 (1)

    1. 2011. "" Bulletin of the Korean Chemical Society, 32(6): 1808~1846     

 저자의 다른 논문

  • Cha, Jin-Soon (63)

    1. 1982 "Asymmetric Reduction of Ketones with Chiral Limonylborane" Bulletin of the Korean Chemical Society 3 (3): 130~131    
    2. 1983 "삼플루오르화붕소에 의한 산화스티렌의 자리옮김" 대한화학회지 = Journal of the Korean Chemical Society 27 (1): 73~75    
    3. 1986 "Attempts on the Preparation of Lithium Trialkoxyborohydrides. Stability and Stereoselective Reduction of Cyclic Ketones" Bulletin of the Korean Chemical Society 7 (1): 66~69    
    4. 1987 "Partial Reduction of Nitriles to Aldehydes by Thexylbromoborane-Methyl Sulfide$^\dag$" Bulletin of the Korean Chemical Society 8 (4): 301~304    
    5. 1987 "Reaction of Di-s-butoxyborane in Tetrahydrofuran with Selected Organic Compounds containing Representative Functional Groups. Catalytic Effect of Tetraalkoxyborate on the Reaction of Dialkoxyborane$^\dag$" Bulletin of the Korean Chemical Society 8 (4): 304~310    
    6. 1987 "Raction of Thexylbromoborane-Methyl Sulfide in Methylene Chloride with Selected Organic Compounds Containing Representative Functional Groups$^\dag$" Bulletin of the Korean Chemical Society 8 (4): 313~318    
    7. 1987 "Enantioselective Reduction of Racemic Three-Membered Heterocyclic Compounds. 3. Reaction of Epoxides with B-Isopinocampheyl-9-borabicycolo[3.3.1]nonane-Potassium Hydride and Potassium B-Isopinocampheyl-9 boratabicyclo[3.3.1]nonane Systems$^1$" Bulletin of the Korean Chemical Society 8 (5): 421~423    
    8. 1988 "Direct Transformation of Carboxylic Acids into Aldehydes through Acyloxy-9-borabicyclo[3.3.1]nonane$^1$" Bulletin of the Korean Chemical Society 9 (1): 48~52    
    9. 1988 "Enantioselective Reduction of Racemic Three-Membered Heterocyclic Compounds. 2. Reaction of Epoxides and Episulfides with (-)-Diisopinocamphenylborane in the Presence of Lithium Chloride$^1$" Bulletin of the Korean Chemical Society 9 (1): 62~64    
    10. 1988 "Facile Reduction of Carboxylic Acid Salts to Aldehydes by Boron Hydrides Thexylbromoborane-Dimethyl Sulfide and 9-Borabicyclo [3.3.1]nonane" Bulletin of the Korean Chemical Society 9 (6): 384~388    

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