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Bulletin of the Korean Chemical Society v.26 no.1, 2005년, pp.77 - 84   피인용횟수: 12

Heterocyclic Nonlinear Optical Chromophores Composed of Phenothiazine or Carbazole Donor and 2-Cyanomethylene-3-cyano-4,5,5-trimethyl-2,5-dihydrofuran Acceptor

Cho, Min-Ju    (College of Environment & Applied Chemistry, Institute of Natural Sciences, Kyung Hee University   ); Kim, Ja-Youn    (College of Environment & Applied Chemistry, Institute of Natural Sciences, Kyung Hee University   ); Kim, Jae-Hong    (College of Environment & Applied Chemistry, Institute of Natural Sciences, Kyung Hee University   ); Lee, Seung-Hwan    (College of Environment & Applied Chemistry, Institute of Natural Sciences, Kyung Hee University   ); Dalton, Larry R.    (Department of Chemistry, University of Washington   ); Choi, Dong-Hoon    (College of Environment & Applied Chemistry, Institute of Natural Sciences, Kyung Hee University  );
  • 초록

    We prepared the new nonlinear optical chromophores that show fairly high microscopic nonlinearity through intramolecular charge transfer. Phenothiazine and carbazole units played an important role to contribute high electron donability and connect the resonance pathway via conjugative effect in the cyclized ring beside the aromatic ring. Theoretical calculation, electrochemical analysis, and absorption spectroscopic study gave us useful information about the energy states and microscopic nonlinearities of two serial chromophores. We compared the microscopic nonlinearities of four chromophores with the conjugation length and electron donability in the push-pull type NLO chromophores. The effect of gradient donability and lengthening the conjugation were investigated on the electronic state and microscopic nonlinearity.


  • 주제어

    Phenothiazine .   Carbazole .   Nonlinear optical chromophore .   Gradient donor moiety.  

  • 참고문헌 (16)

    1. Dalton, L. R.; Harper, A. W.; Wu, B.; Ghosen, R.; Laquin-danum, J.; Liang, Z.; Hubble, A.; Xu, C. Adv. Mater. 1995, 7, 519 
    2. Dalton, L. R.; Harper, A.; Ren, A.; Wang, F.; Todorova, G.; Chen, J.; Zhang, C.; Lee. M. Ind. Eng. Chem. Res. 1999, 38, 8 
    3. Cho, B. R.; Kim, Y. H.; Son, K. W.; Khalil, C.; Kim, Y. H.; Jeon, S.-J. Bull. Korean Chem. Soc. 2002, 23(9), 1253     
    4. Kim, M. H.; Jin, J.-I.; Lee, C. J.; Kim, N.; Park, K. H. Bull. Korean Chem. Soc. 2002, 23(7), 964     
    5. Lee, M.; Katz, H. E.; Erben, C.; Gill, D. M.; Gopalan, P.; Heber, J. D.; McGee, D. J. Science 2002, 298, 1401 
    6. Shi, Y.; Zhang, C.; Zhang, H.; Betchel, J. H.; Dalton, J. R.; Robinson, B. H.; Steier, W. H. Science 2000, 288, 119 
    7. Samyn, C.; Verbiest, T.; Persoons, A. Macromol. Rapid Commun. 2000, 21, 1 
    8. Kramer, C. S.; Zeitler, K.; Muller, T. J. J. Org. Lett. 2000, 2(20), 3723 
    9. Dalton, L. R. Opt. Eng. 2000, 39, 589 
    10. He, M. Q.; Leslie, T. M.; Sinicropi, J. A. Chem. Mater. 2002, 14, 4662 
    11. Wu, X.; Wu, J.; Jen, A. K.-Y. J. Am. Chem. Soc. 1999, 121, 472 
    12. Wang, F.; Ren, A. S.; He, M.; Harper, A. W.; Dalton, L. R.; Zhang, H.; Garner, S. M.; Chen, A.; Steier, W. H. Polym. Prepr. 1998, 39(2), 1065 
    13. Robinson, B. H.; Dalton, L. R.; Harper, A. W.; Ren, A.; Wang, F.; Zhang, C.; Todorova, G.; Lee. M.; Aniszfeld, R.; Garner, S.; Chen, A.; Steier, W. H.; Houbrecht, S.; Persoons, A.; Ledoux, I.; Zyss, J.; Jen, A. K-Y. Chem. Phys. 1999, 245, 35 
    14. Melikian, G.; Rouessac, F. P.; Alexandre, C. Synth. Comm. 1995, 25, 3045 
    15. Dalton, L. R.; Harper, A. W.; Ghosen, R.; Steier, W. H.; Ziari, M.; Fetterman, H.; Shi, Y.; Mustacich, R. V.; Jen, A. K.-Y.; Shea, K. J. Chem. Mater. 1995, 7, 1060 
    16. He, M. Q.; Leslie, T. M.; Sinicropi, J. A.; Garner, S. M.; Reed, L. D. Chem. Mater. 2002, 14, 4669 
  • 이 논문을 인용한 문헌 (12)

    1. 2007. "" Bulletin of the Korean Chemical Society, 28(2): 329~332     
    2. 2007. "" Bulletin of the Korean Chemical Society, 28(8): 1389~1395     
    3. 2007. "" Bulletin of the Korean Chemical Society, 28(8): 1433~1436     
    4. 2007. "" Macromolecular research, 15(7): 595~600     
    5. 2008. "" Bulletin of the Korean Chemical Society, 29(4): 811~816     
    6. 2008. "" Bulletin of the Korean Chemical Society, 29(5): 933~938     
    7. 2008. "" Bulletin of the Korean Chemical Society, 29(1): 181~186     
    8. 2009. "" Bulletin of the Korean Chemical Society, 30(5): 1080~1084     
    9. 2009. "" Bulletin of the Korean Chemical Society, 30(3): 661~666     
    10. 2009. "" Bulletin of the Korean Chemical Society, 30(4): 882~886     
    11. 2009. "" Bulletin of the Korean Chemical Society, 30(3): 731~734     
    12. 2012. "" Bulletin of the Korean Chemical Society, 33(6): 1900~1906     

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