본문 바로가기
HOME> 논문 > 논문 검색상세

논문 상세정보

Bulletin of the Korean Chemical Society v.26 no.1, 2005년, pp.19 - 31   피인용횟수: 2

Excitation Energy Migration in Multiporphyrin Arrays

Hwang, In-Wook   (National Creative Research Initiatives Center for Ultrafast Optical Chearacterisitcs Control and Department of Chemistry, Yonsei UniversityUU0000936  ); Aratani, Naoki   (Department of Chemistry and Core Research for Evolutional Science and Technology (CREST), Kyoto UniversityUU0016178  ); Osuka, Atsuhiro   (Department of Chemistry and Core Research for Evolutional Science and Technology (CREST), Kyoto UniversityUU0016178  ); Kim, Dong-Ho   (National Creative Research Initiatives Center for Ultrafast Optical Chearacterisitcs Control and Department of Chemistry, Yonsei UniversityUU0000936  );
  • 초록

    During the last decade, the exploration of nanoscale device and circuitry based on molecules has gained increasing interest. In parallel with this, considerable effort is being devoted to the development of molecular photonic/electronic materials based on various porphyrin arrays. This involves light as an input/output signal and excitation energy migration as a mechanism for signal transmission. Absorption of a photon at the light collector end of the porphyrin array yields the excited state, which migrates among the intervening pigments until reaching the emitter, whereupon another photon is emitted. As a consequence, it is relevant to understand the excitation energy transfer (EET) processes occurring in various forms of porphyrin arrays for the applications as artificial light harvesting arrays and molecular photonic/electronic wires. Since the excitonic (dipole) and electronic (conjugation) couplings between the adjacent porphyrin moieties in porphyrin arrays govern the EET processes, we have characterized the EET rates of various forms of multiporphyrin arrays (linear, cyclic, and box) based on various time-resolved spectroscopic measurements. We believe that our observations provide a platform for further development of molecular photonic/electronic materials based on porphyrin arrays.


  • 주제어

    Energy transport .   Porphyrin arrays .   Time-resolved spectroscopy .   Dipole coupling .   Light harvesting arrays.  

  • 참고문헌 (50)

    1. McDermott, G. M.; Prince, S. M.; Freer, A. A.; Hawthonthwaite- Lawless, A. M.; Papiz, M. Z.; Cogdell. R. J.; Isaacs, M. W. Nature 1995, 374, 517 
    2. Pullerits, T.; Sundstrom, V. Acc. Chem. Res. 1996, 29, 381 
    3. Holten, D.; Bocian, D. F.; Lindsey, J. S. Acc. Chem. Res. 2002, 35, 57 and references are therein 
    4. Kim, D.; Osuka, A. Acc. Chem. Res. 2004, 37, 735 and references are therein 
    5. Kim, D.; Osuka, A. J. Phys. Chem. A 2003, 107, 8791 and references are therein 
    6. Song, N. W.; Cho, H. S.; Yoon, M.-C.; Aratani, N.; Osuka, A.; Kim, D. Bull. Korean Chem. Soc. 2002, 23, 271 
    7. Cho, H. S.; Rhee, H.; Song, J. K.; Min, C.-K.; Takase, M.; Aratani, N.; Cho, S.; Osuka, A.; Joo, T.; Kim, D. J. Am. Chem. Soc. 2003, 125, 5849 
    8. Hayashi, T.; Ogoshi, H. Chem. Soc. Rev. 1997, 26, 355 
    9. Imamura, T.; Fukushima, K. Coord. Chem. Rev. 2000, 198, 133 
    10. Chernook, A. V.; Rempel, U.; van Borczyskowski, C.; Shulga, A. M.; Zenkevich, E. I. Chem. Phys. Lett. 1996, 254, 229 
    11. Flamigni, L.; Johnson, M. R. New. J. Chem. 2001, 25, 1368 
    12. Hartnell, R. D.; Arnold, D. P. Organometallics 2004, 23, 391 
    13. Cho, H. S.; Song, N. W.; Kim, Y. H.; Jeoung, S. C.; Hahn, S.; Kim, D.; Kim, S. K.; Yoshida, N.; Osuka, A. J. Phys. Chem. A 2000, 104, 3287 
    14. Kim, Y. H.; Jeong, D. H.; Kim, D.; Jeoung, S. C.; Cho, H. S.; Kim, S. K.; Aratani, N.; Osuka, A. J. Am. Chem. Soc. 2001, 123, 76 
    15. Kim, Y. H.; Cho, H. S.; Kim, D.; Kim, S. K.; Yoshida, N.; Osuka, A. Syn. Metal 2001, 117, 183 
    16. Aratani, N.; Osuka, A.; Cho, H. S.; Kim, D. J. Photochem. Photobiol. C: Photochem. Rev. 2002, 3, 25 
    17. Min, C.-K.; Joo, T.; Yoon, M.-C.; Kim, C. M.; Hwang, Y. N.; Kim, D.; Aratani, N.; Yoshida, N.; Osuka, A. J. Chem. Phys. 2001, 114, 6750 
    18. Jeong, D. H.; Yoon, M.-C.; Jang, S. M.; Kim, D.; Cho, D. W.; Yoshida, N.; Aratani, N.; Osuka, A. J. Phys. Chem. A 2002, 106, 2359 
    19. Aratani, N.; Cho, H. S.; Ahn, T. K.; Cho, S.; Kim, D.; Sumi, H.; Osuka, A. J. Am. Chem. Soc. 2003, 125, 9668 
    20. Yoon, M.-C.; Song, J. K.; Cho, S.; Kim, D. Bull. Korean Chem. Soc. 2003, 24, 1075     
    21. Song, N. W.; Cho, H. S.; Yoon, M.-C.; Jeoung, S. C.; Yoshida, N.; Osuka, A.; Kim, D. Bull. Korean Chem. Soc. 2002, 75, 1023 
    22. Tsuda, A.; Osuka, A. Science 2001, 293, 79 
    23. Cho, H. S.; Jeong, D. H.; Cho, S.; Kim, D.; Matsuzaki, Y.; Tanaka, K.; Tsuda, A.; Osuka, A. J. Am. Chem. Soc. 2002, 124, 14642 
    24. Jeong, D. H.; Jang, S. M.; Hwang, I.-W.; Kim, D.; Matsuzaki, Y.; Tanaka, K.; Tsuda, A.; Nakamura, T.; Osuka, A. J. Chem. Phys. 2003, 119, 5237 
    25. Kasha, M. Radiation Res. 1963, 20, 55 
    26. Kasha, M.; Rawls, H. R.; El-Bayoumi, M. A. Pure Appl. Chem. 1965, 11, 371 
    27. Scholes, G. D.; Ghiggino, K. P. J. Phys. Chem. 1994, 98, 4580 
    28. Kakitani, T.; Kimura, A. J. Phys. Chem. A 2002, 106, 2173 
    29. Kimura, A.; Kakitani, T.; Yamato, T. J. Phys. Chem. B 2000, 104, 9276 
    30. Ha, J.-H.; Cho, H. S.; Song, J. K.; Kim, D.; Aratani, N.; Osuka, A. Chem. Phys. Chem. 2004, 5, 57 
    31. Yoon, D. H.; Lee, S. B.; Yoo, K.-H.; Kim, J.; Lim, J. K.; Aratani, N.; Tsuda, A.; Osuka, A.; Kim, D. J. Am. Chem. Soc. 2003, 125, 11062 
    32. Peng, X.; Aratani, N.; Takagi, A.; Matsumoto, T.; Kawai, T.; Hwang, I.-W.; Ahn, T. K.; Kim, D.; Osuka, A. J. Am. Chem. Soc. 2004, 126, 4468 
    33. Nakamura, Y.; Hwang, I.-W.; Aratani, N.; Ahn, T. K.; Ko, D. M.; Takagi, A.; Kawai, T.; Matsumoto, T.; Kim, D.; Osuka, A. J. Am. Chem. Soc. 2005, 127, 236 
    34. Yoshida, N.; Jeong, D. H.; Cho, H. S.; Kim, D.; Matsuzaki, Y.; Tanaka, K.; Osuka, A. Chem. Eur. J. 2003, 9, 58 
    35. Jeong, D. H.; Jang, S. M.; Hwang, I.-W.; Kim, D.; Yoshida, N.; Osuka, A. J. Phys. Chem. A 2002, 106, 11054 
    36. Cho, H. S.; Song, J. K.; Ha, J.-H.; Cho, S.; Kim, D.; Yoshida, N.; Osuka, A. J. Phys. Chem. A 2003, 107, 1897 
    37. Shinmori, H.; Ahn, T. K.; Cho, H. S.; Kim, D.; Yoshida, N.; Osuka, A. Angew. Chem. Int. Ed. 2003, 42, 2754 
    38. Bradforth, S. E.; Jimenez, R.; van Mourik, F.; van Grondelle, R.; Fleming, G. R. J. Phys. Chem. 1995, 99, 16179 
    39. Trinkunas, G. J. Luminescence 2003, 102, 532 
    40. Bruggemann, B.; May, V. J. Chem. Phys. 2004, 120, 2325 
    41. Muller, M. G.; Hucke, M.; Reus, M.; Holzwarth, A. R. J. Phys. Chem. 1996, 100, 9537 
    42. Bruggemann, B.; Herek, J. L.; Sundstrom, V.; Pullerits, T.; May, V. J. Phys. Chem. B 2001, 105, 11391 
    43. Hwang, I.- W.; Cho, H. S.; Jeong, D. H.; Kim, D.; Tsuda, A.; Nakamura, T.; Osuka, A. J. Phys. Chem. B 2003, 107, 9977 
    44. Hwang, I.-W.; Kamada, T.; Ahn, T. K.; Ko, D. M.; Nakamura, T.; Tsuda, A.; Osuka, A.; Kim, D. J. Am. Chem. Soc. 2004, 126, 16187 
    45. Yatskou, M. M.; Koehorst, R. B. M.; Donker, H.; Schaafsma, T. J. J. Phys. Chem. A 2001, 105, 11425 
    46. Wojaczynski, J.; Latos-Grazynski, L. Coord. Chem. Rev. 2000, 204, 113 
    47. Tsuda, A.; Nakamura, T.; Sakamoto, S.; Yamaguchi, K.; Osuka, A. Angew. Chem. Int. Ed. 2002, 41, 2817 
    48. Cho, H. S.; Jeong, D. H.; Yoon, M.-C.; Kim, Y.-R.; Kim, D.; Jeoung, S. C.; Kim, S. K.; Aratani, N.; Shinmori, H.; Osuka, A. J. Phys. Chem. A 2001, 105, 4200 
    49. Aratani, N.; Osuka, A.; Kim, D.; Kim, Y. H.; Jeong, D. H. Angew. Chem. Int. Ed. 2000, 39, 1458 
    50. Trinkunas, G.; Herek, J. L.; Polivka, T.; Sundstrom, V.; Pullerits, T. Phys. Rev. Lett. 2001, 86, 4167 
  • 이 논문을 인용한 문헌 (2)

    1. 2007. "" Bulletin of the Korean Chemical Society, 28(12): 2253~2260     
    2. 2008. "" Bulletin of the Korean Chemical Society, 29(2): 450~462     

 저자의 다른 논문

  • 황인욱 (4)

    1. 2004 "찰나의 화학반응 들여다보기" 광학과 기술 = Optical science and technology 8 (3): 4~9    
    2. 2004 "시간 상관 단일 광자 계수법" 광학과 기술 = Optical science and technology 8 (4): 5~10    

 활용도 분석

  • 상세보기

    amChart 영역
  • 원문보기

    amChart 영역

원문보기

무료다운로드
유료다운로드
  • 원문이 없습니다.

유료 다운로드의 경우 해당 사이트의 정책에 따라 신규 회원가입, 로그인, 유료 구매 등이 필요할 수 있습니다. 해당 사이트에서 발생하는 귀하의 모든 정보활동은 NDSL의 서비스 정책과 무관합니다.

원문복사신청을 하시면, 일부 해외 인쇄학술지의 경우 외국학술지지원센터(FRIC)에서
무료 원문복사 서비스를 제공합니다.

NDSL에서는 해당 원문을 복사서비스하고 있습니다. 위의 원문복사신청 또는 장바구니 담기를 통하여 원문복사서비스 이용이 가능합니다.

이 논문과 함께 출판된 논문 + 더보기