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KIEE international transactions on electrophysics and applications v.5C no.4, 2005년, pp.161 - 164   피인용횟수: 1

Study on Charge Transfer Characteristics of Self-Assembled Viologen Monolayers

Park Sang-Hyun    (Dept. of Electrical Eng. & Port. and Logistics Systems, Dong-A University   ); Lee Dong-Yun    (Dept. of Electrical Eng. & Port. and Logistics Systems, Dong-A University   ); Kwon Young-Soo    (Dept. of Electrical Engineering, Dong-A University  );
  • 초록

    Viologen has been extensively investigated in the paper because their well-behaved electrochemistry has led to their use in a variety of theses, including the electron acceptor for the electric charge delivery mediation of the devices. It was formed monolayer in QCM by self-assembly method. We could know the adsorbed mass of viologen molecules from the frequency shift. We calculated that the adsorbed mass was about 196 [ $ng/cm^2$ ]. We studied the electron transfer property of viologen by the cyclic voltammetry among the electrochemical process so we changed an anion like 0.1 M $NaClO_4$ and $Na_3PO_4$ electrolyte solution and investigated the interrelationship between scan rate and peak current when scan rates were increased twice.


  • 주제어

    viologen .   quartz crystal microbalance(QCM) .   frequency shift .   cyclic voltammetry.  

  • 참고문헌 (10)

    1. N. Nakamura, H. X. Huang, D. J. Qian, J. Miyake, 'Quartz Crystal Microbalance and Electrochemical Studies on a Viologen Thiol Incorporated in Phospholipid Self-Assembled Monolayers' Langmuir, vol.18, pp.5804-5809, 2002 
    2. A. Janshoff, C. Steinem, M. Sieber, A. Baya, M. A. Schmidt, H-J. Galla, 'Quartz crystal microbalance investigation of the interaction of bacterial toxins with ganglioside containing solid supported membranes', Eur Biophys J., vol.26, pp.261-270, 1997 
    3. Q. Feng, W. Yue ,T. M. Cotton, 'Surface-enhanced resonance Raman scattering from methyl viologen at a silver electrode: evidence for two distinct adsorption interactions', J. Phys. Chem., vol.94, pp.2082-2091, 1990 
    4. H. Tatsumi, K. Takagi, M. Fujita, K. Kano, T. Ikeda, 'Electrochemical Study of Reversible Hydrogenase Reaction of Desulfovibrio vulgaris Cells with Methyl Viologen as an Electron Carrier', Anal. Chem., vol.71, pp.1753-1759, 1999 
    5. Abraham Ulman, 'Formation and Structure of Self- Assembled Monolayers', Chem. Rev., vol.96, pp. 1533-1554, 1996 
    6. H. L. Landrum, R. T. Salmon, F. M. Hawkridge, 'A surface-modified gold minigrid electrode which heterogeneously reduces spinach ferredoxin', J. Am. Chem. Soc., vol.99, pp.3154-3158, 1977 
    7. F. M. Hawkridge and T. Kuwana, 'Indirect coulometric titration of biological electron transport compo- nents', Anal. Chem., vol.45, pp.1021-1027, 1973 
    8. W.-K Paik, S. Eu, K. Lee, S. Chon, M. Kim, 'Electrochemical Reactions in Adsorption of Organosulfur Molecules on Gold and Silver Potential Dependent Adsorption', Langmuir, vol.16, pp.10198- 10205, 2000 
    9. J. Y. Ock, H. K. Shin, D. J. Qian, J. Miyake, Y. S. Kwon, 'Determining the Self-Assembling and Redox Process of a Viologen Monolayer by Electrochemical Quartz Crystal Microbalance', Jpn. J. Appl. Phys., vol.43, pp.2376-2380, 2004 
    10. J. Y. Ock, H. K. Shin, S. H. Song, S. M. Chang, D. J. Qian, J. Miyake, Y. S. Kwon, 'The Electrochemical Studies on A Self-Assembled Viologen Monolayer Using Quartz Crystal Microbalance', Mol. Cryst. Liq. Cryst., vol.407, pp.129-134, 2003 
  • 이 논문을 인용한 문헌 (1)

    1. Lee, Dong-Yun ; Park, Sang-Hyun ; Park, Jae-Chul ; Kwon, Young-Soo 2006. "Study on Electrochemical Property of Self-Assembled Viologen Monolayers Using Electrochemical Quartz Crystal Microbalance (EQCM) Method" 전기학회논문지. The transactions of the Korean Institute of Electrical Engineers. C/ C, 전기물성·응용부문, 55(3): 107~110     

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