본문 바로가기
HOME> 논문 > 논문 검색상세

논문 상세정보

Preparation and Characterization of $TiO_2$Filled Sulfonated Poly(ether ether ketone) Nanocomposite Membranes for Direct Methanol Fuel Cells

Kim Han-Joo    (School of Chemical Engineering, Chungbuk National University   ); Kalappa Prashantha    (School of Chemical Engineering, Chungbuk National University   ); Son Won-Keun    (Research Institute of Advanced Materials, Chungnam National University   ); Park Jong-Eun    (Department of Applied Chemistry, Waseda University   ); Oshaka Tetsuya    (Department of Applied Chemistry, Waseda University   ); Kim Hyun-Hoo    (Digital Electronic Department, Dowon Technical College   ); Hong Ji-Sook    (Chemical Engineering Process Center, KRICT   ); Park Soo-Gil    (Dept. of Industrial Chemical Engineering, Chungbuk National University  );
  • 초록

    A series of inorganic-organic hybrid membranes were prepared with a systematic variation of titanium dioxide nanoparticle content. Their water uptake, methanol permeability and proton conductivity as a function of temperature were investigated. The results obtained show that the inorganic oxide network decreases the proton conductivity and water swelling. It is also found that increase in inorganic oxide content leads to decrease of methanol permeability. In terms of the morphology, membranes are homogeneous and exhibit good adhesion between inorganic domains and the polymer matrix. The properties of the composite membranes are compared with the standard nafion membrane.


  • 주제어

    Sulonated Poly Ether Ether Ketone .   Membrane .   Direct Methanol Fuel Cell.  

  • 참고문헌 (18)

    1. S. Surampudi, S.R. Narayanan, E. Vamos, H. Frank, G. Halpert, A. LaConti, J. Kosek, G.K. Surya Prakash and G.A. Olah, 'Advances in direct oxidation methanol fuel cells', J. Power Sources vol. 47, pp. 377-385, 1994 
    2. G. Inzelt, M. Pineri, J.W. Schultze and M.A. Vorotyntsev, 'Electron and proton conducting polymers: recent developments and prospects', Electrochim. Acta., vol. 45 pp. 2403-2410, 2000 
    3. V.S. Silva, B. Ruffmann, H. Silva, Y.A. Gallego, A. Mendas, L.M. Madeira and S.P. Nunes, Proton electrolyte membrane properties and direct methanol fuel cell performance: I. Characterization of hybrid sulfonated poly(ether ether ketone)/zirconium oxide membranes J. Power Sources, vol. 140, no. 10, pp. 34-38, 2005 
    4. V. Baglio, A.S. Arico, A. Di Blasi, V. Antonucci, P.L. Antonucci, S. Licoccia, E. Traversa and F. Serraino Fiory. Nafion-$TiO_2$ composite DMFC membranes: physico-chemical properties of the filler versus electrochemical performance. Electrochimica Acta, vol. 50, pp. 1241-1254, 2005 
    5. L. Jorissen, V. Gogel, J.Kerres and J. Garche, 'New membranes for direct methanol fuel cells', J. Power Sources, vol. 105, no. 2, pp. 267-276, 2002 
    6. O. Savadogo, 'Emerging membranes for electrochemical system. I. Solid polymer membranes for fuel cell systems', J. New Mater. Electr. Syst., vol. 1, pp. 47-52, 1998 
    7. A.S.Arico, S.Srinivasan and V.Antonucci, 'DMFCs: From fundamental aspects to technology development', Fuel Cell, vol. 1, no. 2, pp. 133-135, 2001 
    8. K.A. Kreuer, 'On the development of proton conducting polymer membranes for hydrogen and methanol fuel cells', J. Membr. Sci., vol. 185, pp. 3-8, 2001 
    9. V. Tricoli, 'Proton and methanol transport in poly (perfluorosulfonate) membranes containing $Cs^{+}$ and $H{+}$ cations', J. Electrochem. Soc., vol. 145, pp. 3798- 3805, 1998 
    10. K.T.adjemian, S.J.Lee, S.Srinivasan, J.Benziger and A.B. Bocarsly, 'Silicon oxide nafion composite membranes for proton exchange membrane fuel cell operation at 80-140$^{\circ}C$', J. Electrochem. Soc., vol. 149, no. 3A, pp. 236-243, 2002 
    11. J. Wang, S. Wasmus and R.F. Savinell, 'Evaluation of ethanol, 1-propanol, and 2-propanol in a direct oxidation polymer-electrolyte fuel cell, a real-time mass spectrometry study', J. Electrochem. Soc., vol. 142, pp. 4218-4221, 1995 
    12. B.Kumar, J.P.Fellner, Polymer-Ceramic composite protonic conductors. J.Power Sources, vol. 123, pp. 132-140, 2003 
    13. Peixiang Xing, Gilles P. Robertson, Michael D. Guiver, Serguei D. Mikhailenko, Keping Wang and Serge Kaliaguine. Synthesis and characterization of sulfonated poly(ether ether ketone) for proton exchange membranes J. Membr. Sci. ,vol. 229, pp. 95-100, 2004 
    14. Suzhen Ren, Chennan Li, Xinsheng Zhao, Zhimo Wu, Suli Wang, Gongquan Sun, Qin Xin and Xuefeng Yang, 'Surface modification of sulfonated poly(ether ether ketone) membranes using Nafion solution for direct methanol fuel cell', J.Membr. Sci., vol. 247, pp. 59-65, 2005 
    15. Lei Li, Li Xu and Yuxin Wang, 'Novel proton conducting composite membranes for direct methanol fuel cell', Mater. Lett. Vol. 57, pp. 1406-1421, 2003 
    16. Lei Li, Jun Zhang and Yuxin Wang, 'Sulfonated poly(ether ether ketone) membranes for direct methanol fuel cell', J. Membr. Sci., vol . 226, pp. 159-164, 2003 
    17. M.P. Hogarth and G.A. Hards, 'Direct methanol fuel cells, technological advances and further requirements', Platinum Met. Rev. vol. 40, no. 4, pp. 150-162, 1996 
    18. S. Kaliaguine, S. D. Mikhailenko, K. P. Wang, P. Xing, G. Robertson and M. Guiver, 'Properties of SPEEK based PEMs for fuel cell application', Catalysis Today, vol. 82, pp. 213, 2003 

 저자의 다른 논문

  • 박수길 (47)

    1. 1991 "신기능성 LB 단분자막을 이용한 분자소자의 전기화학적 연구" 공업화학 = Applied chemistry for engineering 2 (4): 311~329    
    2. 1994 "전도성 Polypyrrole의 분해 특성과 물성 개선" 공업화학 = Applied chemistry for engineering 5 (5): 764~771    
    3. 1994 "친핵성 용매하에서 전도성 Polypyrrole의 전기화학적 합성" 공업화학 = Applied chemistry for engineering 5 (4): 616~623    
    4. 1995 "기능성 유기 LB단분자막의 전기화학적 연구" 한국표면공학회지 = Journal of the Korean institute of surface engineering 28 (1): 34~45    
    5. 1996 "알칼리형 연료전지용 La1-xCaxCoO3 기체확산전극의 산소환원반응" 공업화학 = Applied chemistry for engineering 7 (5): 992~998    
    6. 1997 "분산형 전계발광 소자의 발광 특성" 電氣電子材料學會誌= The journal of the Korean Institute of Electrical and Electronic Material Engineers 10 (2): 150~155    
    7. 1997 "리튬전지용 Dimercaptan-Polyphenylenediamine 정극의 제막특성" 공업화학 = Applied chemistry for engineering 8 (1): 114~121    
    8. 1998 "Development of yellow and blue phosphor and their emission properties" 전기화학회지 = Journal of the Korean Electrochemical Society 1 (1): 24~27    
    9. 1998 "폴리우레탄으로 강인화한 페놀수지와 목분 복합체의 물성" 공업화학 = Applied chemistry for engineering 9 (2): 238~242    
    10. 1998 "Poly(ether ether sulfone)의 합성과 술폰화의 최적조건" 공업화학 = Applied chemistry for engineering 9 (2): 249~254    

 활용도 분석

  • 상세보기

    amChart 영역
  • 원문보기

    amChart 영역

원문보기

무료다운로드
  • NDSL :
유료다운로드

유료 다운로드의 경우 해당 사이트의 정책에 따라 신규 회원가입, 로그인, 유료 구매 등이 필요할 수 있습니다. 해당 사이트에서 발생하는 귀하의 모든 정보활동은 NDSL의 서비스 정책과 무관합니다.

원문복사신청을 하시면, 일부 해외 인쇄학술지의 경우 외국학술지지원센터(FRIC)에서
무료 원문복사 서비스를 제공합니다.

NDSL에서는 해당 원문을 복사서비스하고 있습니다. 위의 원문복사신청 또는 장바구니 담기를 통하여 원문복사서비스 이용이 가능합니다.

이 논문과 함께 출판된 논문 + 더보기