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Macromolecular research v.13 no.2, 2005년, pp.141 - 146  

Synthesis and Properties of Calix[4]crown-6 Functionalized Polymers

Kim Su-Han    (Department of Chemistry, Dankook University   ); Lee Chil-Won    (Department of Chemistry, Dankook University   ); Jeon Young-Min    (Department of Chemistry, Dankook University   ); Gong Myoung-Seon    (Department of Chemistry, Dankook University  );
  • 초록

    Calix[4]crown-6-2,4-bis(4-aminobutyl ether), which has a crown-6 moiety at the 1,3-position and amino function at the 2,4-position, was prepared as an intermediate for the subsequent synthesis of calix[4]crown-6-containing polyamide and polyimide using adipoyl chloride and 1,2,4,5-benzenetetracarboxylic dianhydride. The chemical structures were characterized by IR, $^{1}H NMR$ spectroscopy and elemental analysis, and some of their physical properties, including their thermal behavior, were examined. The ion binding characteristics of the monomer and polymers for alkali metal and alkali earth metal ions were measured by liquid-liquid extraction from the aqueous phase into the organic phase. It has been observed that polyamide has a high binding ability towards various metal cations as compared to polyimide, which showed cesium ion selectivity.


  • 주제어

    calix[4]crown-6 .   polyamide .   polyimide .   ion-binding.  

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 저자의 다른 논문

  • Kim Su-Han (2)

    1. 2004 "Preparation and Ion-Binding Properties of Calix[4]crown-Containing Polyesters" Bulletin of the Korean Chemical Society 25 (8): 1265~1268    
    2. 2005 "Preparation and Properties of Calix[4]arene-Based Epoxy Resins" Macromolecular research 13 (6): 553~556    
  • Lee, Chil Won (12)

  • 전영민 (9)

  • Gong, Myoung-Seon (54)

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