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Macromolecular research v.13 no.1, 2005년, pp.14 - 18   피인용횟수: 1

Using Microwave Irradiation to Prepare New Poly(amide-imide)s Containing Tetrahydropyrimidinone, Tetrahydro-2-thioxopyrimidine, and Trimellitic Rings in Their Main Chains: Synthesis and Characterization

Faghihi Khalil    (Organic Polymer Chemistry Research Laboratory, Department of Chemistry, Faculty of Science, Arak University, Dept. of Chemical Eng., Faculty of Eng., Azad University of Arak   ); Hagibeygi Mohsen    (Dept. of Chemical Eng., Faculty of Eng., Azad University of Arak  );
  • 초록

    Under irradiation in a microwave oven, six novel poly(amide-imide)s containing tetrahydropyrimidinone, tetrahydro-2-thioxopyrimidine moieties and trimellitic rings in their main chains were synthesized through the polycondensation reaction of N,N'-(4,4'-diphenylether)bis(trimellitimide) diacid chloride with six different derivatives of tetrahydropyrimidinone and tetrahydro-2-thioxopyrimidine in the presence of a small amount of a polar organic medium, such as o-cresol. The polycondensation proceeded rapidly and completed within 7-9 min, producing a series of new poly(amide-imide)s in high yield that showed inherent viscosities in the range 0.33-0.52 dL/g. These poly(amide-imide)s were characterized by elemental analysis, viscosity measurement, thermal gravimetric analysis, solubility test, and FT-IR spectroscopy. All of the polymers were soluble at room temperature in polar solvents such as N,N-dimethylacetamide, N,N-dimethylformamide, dimethylsulfoxide, tetrahydrofuran, and N-methyl-2-pyrrolidone.


  • 주제어

    poly(amide-imide)s .   polycondensation .   microwave irradiation .   characterization .   thermally-stable poly­mers.  

  • 참고문헌 (27)

    1. V. Baudel, F. Cazier, P. Woisel, and G. Surpateanu, Eur. Polym. J., 38, 615 (2002) 
    2. S. Caddick, Tetrahedron, 38, 10403 (1995) 
    3. U. Hottong, J. Wei, R. Dhulipala, and M. C. Hawley, Ceram. Trans., 21, 587 (1991) 
    4. S. E. Mallakpour, A. R. Hajipour, Kh. Faghihi, N. Foroughifar, and J. Bagheri, J. Appl. Polym. Sci., 80, 2416 (2001) 
    5. W. Zhang, J. I. Jin, and R. W. Lenz, Makromol. Chem., 189, 2219 (1988) 
    6. W. R. Krigbaum, H. Hakemi, and R. Kotek, Macromolecules, 18, 965 (1985) 
    7. H. Yeganeh, M. Barikani, and F. N. khodabadi, Eur. Polym. J., 36, 2207 (2000) 
    8. S. R. Varma, Green Chem., 1, 43 (1999) 
    9. D. Esfandiary, Synthesis of New Different Derivatives of Tetrahydropyrimidinone and Tetrahydro-2-thioxopyrimidine Compounds, M. S. Thesis, University of Arak, Arak, Iran, 1999 
    10. M. J. M. Abadie and B. Sillion, Polyimide and Other High- Temperature Polymers, Elesevier, New York, 1991 
    11. P. Lidstrom, J. Tierney, B. Wathey, and J. Westman, Tetrahedron, 57, 9225 (2001) 
    12. Z. Jedlinski, J. Franek, K. Uryu, J. C. Song, and T. Kato, Polym. J., 21, 409 (1989) 
    13. S. Watanabe, K. Hayama, K. H. Park, M. Kakimoto, and Y. Imai, Macromol. Chem. Rapid Commun., 14, 481 (1993) 
    14. Kh. Faghihi, Kh. Zamani, A. Mirsamie, and M. R. Sangi, Eur. Polym. J., 39, 247 (2003) 
    15. Kh. Faghihi, Kh. Zamani, A. Mirsamie, and S. Mallakpour, Polym. Int., 53, 1226 (2004) 
    16. T. C. Ward and M. Chen, Polym. Mater. Sci. Eng., 66, 335 (1992) 
    17. S. E. Mallakpour, A. R. Hajipour, and Kh. Faghihi, Eur. Polym. J., 37, 119 (2001) 
    18. M. K. Ghosh and K. L. Mittal, Polyimide: Fundamentals and Applications, Elesevier, New York, 1996 
    19. Y. Peng and G. Song, Green Chem., 3, 302 (2001) 
    20. H. Jullien and H. Valot, Polym., 26, 505 (1985) 
    21. D. A. Lewis, Mater. Res. Soc. Symp. Proc., 269, 21 (1992) 
    22. S. E. Mallakpour, A. R. Hajipour, and Kh. Faghihi, Polym. Int., 49, 1383 (2000) 
    23. J. P. Chen and A. Natansohn, Macromolecules, 32, 3171 (1999) 
    24. J. Wei, J. D. DeLong, M. DeMeuse, and M. C. Hawley, Polym. Eng. Sci., 33, 1132 (1993) 
    25. C. O. Kappe, Acc. Chem. Res., 33, 879 (2000) 
    26. Kh. Faghihi, Kh. Zamani, A. Mirsamie, and S. Mallakpour, J. Appl. Polym. Sci., 91, 516 (2004) 
    27. J. Mijovic, A. Fishbain, and J. Wijaya, Macromolecules, 25, 986 (1992) 
  • 이 논문을 인용한 문헌 (1)

    1. 2010. "" Macromolecular research, 18(1): 2~7     

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