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Analysis of Agrochemical Residues in Tobacco Using QuEChERS Method by GC-MS/MS

Lee, Jeong-Min   (KT&G Central Research InstituteCC0187146  ); Jang, Gi-Chul   (KT&G Central Research InstituteCC0187146  ); Hwang, Keon-Joong   (KT&G Central Research InstituteCC0187146  );
  • 초록

    This study was performed to apply the more rapid and accurate sample preparation, and the high selectivity and sensitivity of the analyte detection by gas chromatography-triple quadrupole mass spectrometry (GC-MS/MS). QuEChERS (quick, easy, cheap, effective, rugged and safe) method was validated for 49 agrochemicals in the CORESTA Agrochemical Advisory Committee guide and amenable to GC-MS/MS determination. In QuEChERS method, the effects of sorbents (PSA, $C_{18}$ and GCB) and matrix of the analytes in tobacco types (flue-cured, burley and oriental) were investigated. MS/MS acquisition provided high specificity and selectivity for agrochemicals and low limit of quantification. QuEChERS by using PSA alone and the matrix-matched standards gave good recoveries and RSD values in three types of tobaccos. QuEChERS method was no needed to be complex clean-up procedure and would be used as the fast and easy method for agrochemical residue analysis in tobacco.


  • 주제어

    Tobacco .   agrochemicals .   QuEChERS .   GC-MS/MS.  

  • 참고문헌 (12)

    1. Anspach T. (2006) QuEChERS Multi Residue Method - an Effective Tool for the Determination of Agrochemical Residues in Tobacco by LC-MS/MS. CORESTA, PT22 
    2. Barrio, C. S., Asensio, J. S. and Bernal J. (1994) GC-NPD investigation of the recovery of organonitrogen and organophosphorus pesticides from apple samples: The effect of the extraction solvent. Chromatographia 39: 320-324 
    3. CORESTA (2003) CORESTA Guide No.1 - The concept and implementation ofagrochemic-alguidance residue levels 
    4. Frenich, A. G., Gonzalez-Rodriguez, M. J., Arrebola, F. J. and Martinez Vidal, J. L. (2005) Potentiality of gas chromatography-triple quadrupole mass spectrometry in vanguard and rearguard methods of pesticide residues in vegetables. Anal. Chem. 74: 4640-4648 
    5. International Standard Organization (2000) Tobacco and tobacco products - Determination of organochlorine pesticide residue - gas chromatographic method, International Standard Organization, ISO 4389:2000(E), Geneva 
    6. Anastassiades, M., Lehotay, S. J., Stajnbaher, D. and Schenck, F. J. (2003) QuEChERS - A new sample preparation technique for multiresidue analysis of pesticides in foods and agricultural samples. J. AOAC Int. 86: 412-431 
    7. Haib, J., Hofer, I. and Renaud, J. M. (2003) Analysis of multiple pesticide residues in tobacco using pressurized liquid extraction, automated solid-phase extraction clean-up and gas chromatography-tandem mass spectrometry. J. Chromatogr. A 1020: 173-187 
    8. Mueller, L. and Ward, M. R. (1999) Tobacco production, chemistry and technology, pp. 250-264, Davis, D. L. and Nielsen, M. T. eds., Blackwell, London, UK 
    9. Albero, B., Sanchez-Brunete, C. and Tadeo, J. L. (2004) Analysis of pesticides in honey by solid-phase extraction and gas chromatographymass spectrometry. J. Agric. Food Chem. 52: 5828 -5835 
    10. Dugo, G., Bella, G. D., Torre, L. L. and Saitta, M. (2005) Rapid GC-FPD determination of organophosphorus pesticide residues in Sicilian and Apulian olive oil. Food Control 16: 435-438 
    11. Lehotay, S. J., Mastovska, K. and Yun, S. J. (2005) Evaluation of two fast and easy methods for pesticide residue analysis in fatty food matrices. J. AOAC Int. 88: 630-638 
    12. Tahboub, Y. R., Zaater, M. F. and Al-Talla, Z. A. (2005) Determination of the limits of identification and quantitation of selected organochlorine and organophosphorus pesticide residues in surface water by full-scan gas chromatography/mass spectrometry. J. Chromatogr. A 1098: 150-155 

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