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아파트 실내 환경에서 실시간 측정시스템을 활용한 HONO 농도 측정 및 생성기작 연구
Determination of HONO Concentration and Investigation on Its Formation Mechanism Using a Continuous Measurement System in Indoor Environment of an Apartment

박승식   (전남대학교 환경공학과UU0001112  ); 홍진의   (광주과학기술원 환경공학과 환경모니터링 신기술 연구센터UU0000201  ); 이재훈   (광주과학기술원 환경공학과 환경모니터링 신기술 연구센터UU0000201  ); 김영준   (광주과학기술원 환경공학과 환경모니터링 신기술 연구센터UU0000201  ); 조성용   (전남대학교 환경공학과UU0001112  ); 김승재   (전남대학교 환경공학과UU0001112  );
  • 초록

    Nitrous acid (HONO) can be produced by heterogenous reactions of nitrogen dioxide on surface materials and direct emission from combustion sources. However, a little is known of indoor HONO levels or the relationship between residential HONO, NO, and $NO_2$ concentrations in occupied houses. Therefore, we measured simultaneously NO, $NO_2$ , and HONO concentrations in living room of an apartment using continuous analyzers to study the production of HONO (June $22{\sim}30$ , 2006). The 4-min average concentrations of indoor NO, $NO_2$ , and HONO were 4.3 (range: $0.4{\sim}214.3$ ), 10.3 ( $2.0{\sim}87.3$ ), and 1.8 ppb ( $0.3{\sim}7.7$ ), respectively. Peak levels of HONO up to 7.7 ppb and 24-hr averages as high as 1.7 ppb were measured. In agreement with previous studies, indoor HONO concentrations increased during operation of an unvented gas range. Examination of the observed kinetics suggests that the secondary production of indoor HONO, possibly as a result of heterogeneous reactions involving $NO_2$ and $H_2O$ is associated with $[NO_2]^2[H_2O]\;(r^2=0.88)$ rather than with $[NO][NO_2][H_2O]\;(r^2=0.75)$ . Three combustion experiments at nighttime were also carried out to investigate the effects of vented combustion on the HONO, NO, and $NO_2$ concentrations. It was found to release HONO for $10{\sim}15$ minutes after NO and $NO_2$ source was turned off, and peak values were finally attained. Compared to unvented combustion, peak $NO_2$ and HONO concentrations were 3.2 and 2.0 times lower at weak vented combustion (air flow: $340\;m^3/hr$ ) and 4.9 and 2.4 times lower at strong vented combustion (air flow: $540\;m^3/hr$ ), respectively, emphasizing importance of operating ventilation hood fan during combustion to improve indoor air quality.


  • 주제어

    Nitrogen dioxide .   Nitrous acid .   Indoor air .   Heterogeneous reaction .   Gas burning.  

  • 참고문헌 (40)

    1. 백성옥, 김윤신(1998) 도시지역 실내환경 유형별 공기질 특 성평가-가정, 사무실 및 식당을 중심으로, 한국대기보전학회지, 14(4), 343-360 
    2. Alicke, B., A. Geyer, A. Hofzumahaus, F. Holland, S. Konrad, H.W. Patz, J. Schafer, J. Stutz, A. Volz-Thomas, and U. Platt (2003) OH formation by HONO photolysis during the BERLIOZ experiment, Journal of Geophysical Research, 108(D4), 8247, doi:10.1029 /2001/JD00579 
    3. Andres-Hernandez, M.D., J. Notholt, J. Hjorth, and O. Schrems (1996) A DOAS study on the origin of nitrous acid at urban and non-urban sites, Atmospheric Environment, 30, 175-180 
    4. Brauer, M., P.B. Ryan, H.H. Suh, P. Koutrakis, and J.D. Spengler (1990) Measurements of nitrous acid inside two research houses, Environmental Science and Technology, 24, 1521-1527 
    5. Febo, A. and C. Perrino (1991) Prediction and experimental evidence for high air concentration of nitrous acid in indoor environments, Atmospheric Environment, 25A, 1055-1061 
    6. Lee, H.S., B.-W. Kang, J.-P. Cheong, and S.-L. Lee (1997) Relationship between indoor and outdoor air quality during the summer season in Korea, Atmospheric Environment, 31, 1689-1693 
    7. Lee, Y.N. and S.E. Schwartz (1981) Evaluation of the rate of uptake of nitrogen dioxide by atmospheric and surface liquid water, Journal of Geophysical Research, 86, 11971-11983 
    8. Pitts, J.N., E. Sanhueza, R. Atkinson, W.P.L. Carter, A.M. Winer, G.W. Harris, and C.N. Plum (1984) An investigation of the dark formation of nitrous acid in environmental chambers, International Journal of Chemistry Kinetics, 16, 919-939 
    9. Rasmussen, T.R., M. Brauer, and S. Kjaergaard (1995) Effects of nitrous acid exposure on human mucous membranes, American Journal of Respiratory and Critical Care Medicine, 151, 1504-1511 
    10. Sohn, D.H., W.K. Shin, S.Y. Jung, and W.T. Jung (1995) Determination of indoor air pollution of Seoul by nitrogen dioxide using a Palmes tube air sampler, Japanese Journal of Toxicology and Environmental Health, 41, 127-133 
    11. Stutz, J., B. Alicke, R. Ackermann, A. Geyer, S. Wang, A.B. White, E.J. Williams, C.W. Spicer, and J.D. Fast (2004) Relative humidty dependence of HONO chemistry in urban areas, Journal of Geophysical Research, 109, D03307 
    12. U.S. EPA (1993) Air quality criteria for oxides of nitrogen. EPA-600/8-91/049-F. Washington,D.C., U.S. Environmental Protection Agency 
    13. 홍진의, 이재훈, 박승식(2007) 실시 측정시스템을 활용한 실 내 환경에서 HONO 농도 조사, 한국대기환경학회지, 23(2), 191-202     
    14. Calvert, J.G., G. Yarwood, and A.M. Dunker (1994) An evaluation of the mechanism of nitrous acid formation in the urban atmosphere, Research on Chemical Intermediates, 20, 463-502 
    15. Reisinger, A.R. (2000) Observations of $HNO_2$ in the polluted winter atmosphere: possible heterogeneous production on aerosols, Atmospheric Environment, 34, 3865-3874 
    16. Jenkin, M.E., R.A. Cox, and D.J. Williams (1988) Laboratory studies of the kinetics of formation of nitrous acid from the thermal reaction of nitrogen dioxide and water vapour, Atmospheric Environment, 22, 487- 498 
    17. Sakamaki, F., S. Hatakeyama, and H. Akimoto (1983) Formation of nitrous acid and nitric oxide in the heterogeneous dark reaction of nitrogen dioxide and water vapor in a smog chamber, International Journal of Chemistry Kinetics, 15, 1013-1029 
    18. Samet, J.M., M.C. Marbury, and J.D. Spengler (1987) Health effects and sources of indoor air pollution, part I, American Review Respiratory Disease, 138, 1496- 1508 
    19. Park, S.S., S.B. Hong, Y.G. Jung, and J.H. Lee (2004) Measurements of $PM_{10}$ aerosol and gas-phase nitrous acid during fall season in a semi-urban atmosphere, Atmospheric Environment, 38, 293-304 
    20. 정상진, 장재철(2004) Methyl yellow와 Methyl orange 지시 약을 이용한 실내공기 중의 포름알데히드 간이측 정기에 대한 연구, 한국대기환경학회지, 20(6), 793-801     
    21. Leaderer, B.P., L. Naeher, K. Balenger, T.R. Holford, C. Toth, J. Sullivan, J.M. Wolfson, and P. Koutrakis (1999) Indoor, outdoor, and regional summer and winter concentrations of $PM_{10},\;PM_{2.5},\;{SO_4}^{2-},\;H^+,\;{NH_4}^+,\;{NO_3}^-,\;NH_3,$ and nitrous acid in homes with and without kerosene space heaters, Environmental Health Perspectives, 107, 223-231 
    22. Notholt, J., J. Hjorth, and F. Raes (1992) Formation of $HNO_2$ on aerosol surfaces during foggy periods in the presence of NO and $NO_2$, Atmospheric Environment, 26A, 211-217 
    23. Brauer, M., T.R. Rasmussen, S.K. Kjaergaard, and J.D. Spengler (1993) Nitrous acid formation in an experimental exposure chamber, Indoor Air, 3, 94-105 
    24. Farrow, A., R. Greenwood, S. Preece, and J. Golding (1997) Nitrogen dioxide, the oxides of nitrogen and infants' health symptoms, Archives of Environmental Health, 52, 189-194 
    25. Brauer, M., P. Koutrakis, G.J. Keeler, and J.D. Spengler (1991) Indoor and outdoor concentrations of inorganic acidic aerosols and gases, Journal of the Air & Waste Management Association, 41, 171-181 
    26. Brink, H.M.T. and H. Spolestra (1998) The dark decay of hono in environmental (SMOG) chambers, Atmospheric Environment, 32, 247-251 
    27. Schwartz, S.E. and W.H. White (1983) In Trace Atmospheric Constituents: Properties, Transformations and Fates; Advances in Environmental Science and Technology 12, Edited by Schwartz, S.E., 1-116 
    28. Gerecke, A., A. Thielmann, L. Gutzwiller, and M.J. Rossi (1998) The chemical kinetics of HONO formation resulting from heterogeneous interaction of $NO_2$ with flame soot, Geophysical Research Letters, 25, 2453-2456 
    29. Goldstein, I.F., L.R. Andrews, and D. Hartel (1988) Assessment of human exposure to nitrogen dioxide, carbon monoxide and respirable particulates in New York inner-city residences, Atmospheric Environment, 22, 2127-2139 
    30. Jarvis, D.L., B.P. Leaderer, S. Chinn, and P.G. Burney (2005) Indoor nitrous acid and respiratory symptoms and lung function in adults, Environmental Exposure, 60, 474-479 
    31. Goodman, A.L., G.M. Underwood, and V.H. Grassian (1999) Heterogeneous reaction of $NO_2$: Characterization of gas-phase and adsorbed products from the reaction, $2NO (g)+H_2O (a) \rightarrow HONO (g)+HNO_3 (a)$ on hydrated silica particles, Journal of Physical Chemistry A, 103, 7217-7223 
    32. Allen, A.G. and A.H. Miguel (1995) Indoor organic and inorganic pollutants: in-situ formation and dry deposition in Southeastern Brazil, Atmospheric Environment, 29, 3519-3526 
    33. Beckett, W.S., M.B. Russi, A.D. Haber, R.M. Rivkin, J.R. Sullivan, Z. Tameroglu, V. Mohsenin, and B.P. Leaderer (1995) Effect of nitrous acid exposure on lung function in asthmatics: a chamber study, Environmental Health Perspectives, 103, 372-375 
    34. Platt, U., D. Perner, G.W. Harris, A.M. Winer, and J.N. Pitts (1980) Observation of nitrous acid in an urban atmosphere by differential optical absorption, Nature, 285, 312-314 
    35. Ammann, M., M. Kalberer, D.T. Jost, L. Tobler, E. Rssler, D. Piguet, H.W. Gggler, and U. Baltensperger (1998) Heterogeneous production of nitrous acid on soot in polluted air masses, Nature, 395, 157-160 
    36. Lammel, G. and J.N. Cape (1996) Nitrous acid and nitrite in the atmosphere, Chemical Society Reviews, 25, 361-369 
    37. Spengler, J.D., M. Brauer, J.M. Samet, and W.E. Lambert (1993) Nitrous acid in Albuquerque, New Mexico, homes, Environmental Science and Technology, 27, 841-845 
    38. Spicer, C.W., D.V. Kenny, G.F. Ward, and I.H. Billick (1993) Transformations, lifetime, and sources of $NO_2$, HONO and $HNO_3$ in indoor environments, Journal of the Air and Waste Management, 43, 1479-1485 
    39. Lee, K., X. Jianping, A.S. Geyh, H. Ozkaynak, B.P. Leaderer, C.J. Weschler, and J.D. Spengler (2002) Nitrous acid, nitrogen dioxide, and ozone concentrations in residential environments, Environmental Health Perspectives, 110, 145-149 
    40. Kleffmann, J., K.H. Becker, and P. Wiesen (1998) Heterogeneous $NO_2$conversion processes on acid surfaces: possible atmospheric implications, Atmospheric Environment, 32, 2721-2729 
  • 이 논문을 인용한 문헌 (1)

    1. Lim, Heung-Bin ; Kim, Seung-Hyung 2008. "Enhancement of Allergen-related Eosinophilic Airway Inflammation and Airway Hyperresponsiveness by House Dust Particles in Mice" 한국대기환경학회지 = Journal of Korean Society for Atmospheric Environment, 24(3): 321~328     

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