본문 바로가기
HOME> 논문 > 논문 검색상세

논문 상세정보

Fibers and polymers v.10 no.4, 2009년, pp.437 - 441   피인용횟수: 1

Infrared Analysis of the Amino Group Content in Functional Aminopolydimethylsiloxanes

Gutierrez, M.C.    (INTEXTER (Universitat Politecnica de Catalunya)   ); Lopez-Mesas, M.    (Departament de Quimica, Unitat Q. Analitica, Centre GTS, Facultat de Ciencies, Universitat Autonoma de Barcelona,   ); Lacorte, M.T.    (Departamento de Ciencia de Materiales, Universitat Politecnica de Catalunya   ); Cegarra, J.    (INTEXTER (Universitat Politecnica de Catalunya)  );
  • 초록

    In the present work, a new method for the analysis of the amino group content in different amino polydimethylsiloxanes (silicones) by infrared analysis has been developed. Because of the low ratio of the amino functional group present in the silicone molecules (which is sufficient to modify their properties), its analysis by traditional techniques is tedious and complex. The novelty of this study relies on the fast and easy application of the Fourier transform infrared spectroscopy (FTIR) to the quantitative analysis of these groups by the use of low intensity bands. With this purpose, spectra obtained from samples with different polymerization degree and/or amino group content have been compared to select a characteristic band for the amino group and another for the siloxane bond to be used as reference band. From the calibration curve obtained, two different samples of known amount of amino group content were analyzed obtaining a good correlation with the value found by the experimental design.


  • 주제어

    Silicone .   Polysiloxane .   Aminosiloxane .   Ethylenediamino group .   Infrared spectroscopy.  

  • 참고문헌 (18)

    1. B. Sandner, ITB Tintoreria/Acabado/Estampado, 4, 50 (1995) 
    2. E. D. Lipp, Appl. Spectrosc., 40, 1009 (1986) 
    3. H. M. Klimisch, G. S. Kohl, and J. M. Sabourin, J. Soc. Cosmet. Chem., 38, 247 (1987) 
    4. H. J. Lautenschlager, J. Bindl, and K. G. Huhn, Textil Praxis International, 5, 460 (1992) 
    5. M. Pesez and J. Bartos, 'Colorimetric and Fluorimetric Analysis of Organic Compounds and Drugs', Marcel Dekker Inc., New York, 1974 
    6. A. L. Smith, 'Analysis of Silicones', Robert E. Krieger Publishing Company: Malabar-Florida, 1983 
    7. M. C. Guti$\acute{e}$rrez and J. Cegarra, 'Analysis of Aminopoly-Siloxanes Employed as Softeners', In Proceedings of 19th IFATCC Meeting, Paris (France), CH-19, 2002 
    8. M. W. Skinner, C. Qian, S. Grigoras, D. J. Halloran, and B. L. Zimmerman, Text. Res. J., 69, 935 (1999) 
    9. R. S. S. Murthy, D. E. Leyden, and R. P. D’Alonzo, Appl. Spectrosc., 39, 856 (1985) 
    10. K. Esko, S. Karlson, and J. Porath, Acta Chemica Scandinavica, 22, 3342 (1968) 
    11. P. Habereder, Melliand International, 8, 143 (2002) 
    12. F. De Buyl, Int. J. Adhes., 21, 411 (2001) 
    13. S. M. G. Patel, S. M. N. Chapatwala, and R. S. Gandhi, Textile Dyer and Printer, 6, 26 (1989) 
    14. M. C. Guti$\acute{e}$rrez and J. Cegarra, 'Relationship between the Molecular Weight and the Intrinsic Viscosity of Aminopolydimethylsiloxanes', Chemical Engineerig Technology, ECCE-4 Abstracts on Line, P-10, 1-027, 2004 
    15. E. Yilgor, I. Yilgor, and S. Suzer, Polymer, 44, 7271 (2003) 
    16. A. Bereck, D. Riegel, B. Weber, J. Mosel, J. Bindl, P. Habereder, K. G. Huhn, H. J. Lautenschlager, and G. Preiner, Textilveredlung, 32, 158 (1997) 
    17. G. O. Yahaya, B. J. Brisdon, M. Maxwell, and R. England, J. Appl. Polym. Sci., 82, 808 (2001) 
    18. M. C. Burrell, M. D. Butts, D. Derr, S. Genovese, and R. J. Perry, Appl. Surf. Sci., 227, 1 (2004) 
  • 이 논문을 인용한 문헌 (1)

    1. 2010. "" Korea-Australia rheology journal, 22(3): 205~210     

 활용도 분석

  • 상세보기

    amChart 영역
  • 원문보기

    amChart 영역

원문보기

무료다운로드
  • 원문이 없습니다.
유료다운로드

유료 다운로드의 경우 해당 사이트의 정책에 따라 신규 회원가입, 로그인, 유료 구매 등이 필요할 수 있습니다. 해당 사이트에서 발생하는 귀하의 모든 정보활동은 NDSL의 서비스 정책과 무관합니다.

원문복사신청을 하시면, 일부 해외 인쇄학술지의 경우 외국학술지지원센터(FRIC)에서
무료 원문복사 서비스를 제공합니다.

NDSL에서는 해당 원문을 복사서비스하고 있습니다. 위의 원문복사신청 또는 장바구니 담기를 통하여 원문복사서비스 이용이 가능합니다.

이 논문과 함께 출판된 논문 + 더보기