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Korea-Australia rheology journal v.22 no.1, 2010년, pp.43 - 50   SCIE 피인용횟수: 1
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Molecule-based electrorheological material assembled using $\beta$-cyclodextrin as substrate

Shang, Yan-Li    (Beijing National Laboratory for Molecular Science, (State Key Laboratory of Rare Earth Materials Chemistry and Applications), College of Chemistry and Molecular Engineering, Peking University   ); Jia, Yun-Ling    (Beijing National Laboratory for Molecular Science, (State Key Laboratory of Rare Earth Materials Chemistry and Applications), College of Chemistry and Molecular Engineering, Peking University   ); Ma, Yun    (Beijing National Laboratory for Molecular Science, (State Key Laboratory of Rare Earth Materials Chemistry and Applications), College of Chemistry and Molecular Engineering, Peking University   ); Li, Jun-Ran    (Beijing National Laboratory for Molecular Science, (State Key Laboratory of Rare Earth Materials Chemistry and Applications), College of Chemistry and Molecular Engineering, Peking University   ); Zhang, Shao-Hua    (School of Vehicle and Transmission Engineering, Beijing Institute of Technology   ); Li, Ming-Xiu    (Department of Chemistry, Hebei Normal University  );
  • 초록

    Molecule-based electrorheological (ER) materials as a novel type of ER materials, the inclusion compound [ $H_2$ ( $\beta$ -CD-A)-PTA] between p-toluenesulfonic acid (PTA, guest) and $H_2$ ( $\beta$ -CD-A) (host) that is dicarboxylic acid of $\beta$ -cyclodextrin ( $\beta$ -CD), and the rare earth (RE) complexes [( $\beta$ -CD-A)-PTA] $_3RE_2$ (RE=La, Gd, Y) of $H_2$ ( $\beta$ -CD-A)-PTA, were synthesized. The ER performance and dielectric property of the materials were studied. Our results show that the molecule-based ER materials assembled using $\beta$ -cyclodextrin as a substrate, especially the inclusion compound and its rare earth (RE) complexes exhibit clear ER effect. The inclusion PTA can markedly enhance the ER performance of $H_2$ ( $\beta$ -CD-A) material. The ER activity of the yttrium complex is the highest among these materials. The characteristic of the molecule in molecule-based ER materials is an important factor in influencing ER property.


  • 주제어

    electrorheological material .   chemical synthesis .   electrorheological property.  

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  • 이 논문을 인용한 문헌 (1)

    1. 2013. "" Korea-Australia rheology journal, 25(1): 9~18     

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