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Macromolecular research v.18 no.6, 2010년, pp.577 - 582   SCI SCIE 피인용횟수: 2
본 등재정보는 저널의 등재정보를 참고하여 보여주는 베타서비스로 정확한 논문의 등재여부는 등재기관에 확인하시기 바랍니다.

Preparation and Characterization of a Cation Exchange Membrane Using a Styrene-Hydroxyethyl Acrylate-Lauryl Methacrylate Terpolymer

Choi, Eun-Mi    (Department of Chemical Engineering, College of Engineering, Chungnam National University   ); Shin, Kyoung-Sub    (Department of Chemical Engineering, College of Engineering, Chungnam National University   ); Hwang, Taek-Sung    (Department of Chemical Engineering, College of Engineering, Chungnam National University  );
  • 초록

    A novel cation exchange membrane based on a styrene-hydroxy ethyl acrylate-lauryl methacrylate terpolymer (St-HEA-LMA) was prepared. Sulfonic groups were introduced to the membrane structure with sulfuric acid as the sulfonating agent and silver sulfate as the initiator. Sulfonated St-HEA-LMA terpolymer membranes were characterized by Fourier-transform infrared (FTIR) spectroscopy and atomic force microscopy (AFM), as well as by determining the degree of sulfonation (DS), ion-exchange capacity (IEC), swelling ratio and electrical resistance of the membranes. The presence of sulfonic groups in the sulfonated St-HEA-LMA terpolymer was confirmed by FTIR, and the resulting membrane exhibited an ion-exchange capacity of 2.13 meq/g and an electrical resistance of 1.17 $\Omega{\cdot}cm^2$ . The swelling ratio of the prepared membranes increased with increasing degree of sulfonation, and the tensile strength decreased with increasing degree of sulfonation at a reaction temperature of $30^{\circ}C$ . The phase images obtained by AFM clearly showed an increase in roughness with increasing DS. Considering the mechanical properties, the sulfonated St-HEA-LMA terpolymer obtained at a sulfonation reaction temperature of $20^{\circ}C$ was suitable for ion-exchange membrane applications.


  • 주제어

    ion-exchange membrane .   terpolymer .   sulfonation .   electrical property .   ion-exchange capacity.  

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  • 이 논문을 인용한 문헌 (2)

    1. 2012. "" Macromolecular research, 20(8): 827~834     
    2. Mun, Hye Jin ; Choi, Jae Hak ; Hong, Young Taik ; Chang, Bong Jun 2015. "The Preparation and Electrochemical Properties of Pore-filled and Polystyrene-based Anion-exchange Membranes Using Poly(ethylene glycol)methyl Ether Methacrylate" 멤브레인 = Membrane Journal, 25(6): 515~523     

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