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한국결정성장학회지 = Journal of the Korean crystal growth and crystal technology v.22 no.2, 2012년, pp.84 - 91   피인용횟수: 1
본 등재정보는 저널의 등재정보를 참고하여 보여주는 베타서비스로 정확한 논문의 등재여부는 등재기관에 확인하시기 바랍니다.

NO2 gas sensing based on graphene synthesized via chemical reduction process of exfoliated graphene oxide

Khai, Tran Van    (Department of Materials Science and Engineering, Hanyang University   ); Prachuporn, Maneeratanasarn    (Department of Materials Science and Engineering, Hanyang University   ); Shim, Kwang-Bo    (Department of Materials Science and Engineering, Hanyang University  );
  • 초록

    Single and few-layer graphene nanosheets (GNs) have successfully synthesized by a modified Hummer's method followed by chemical reduction of exfoliated graphene oxide (GO) in the presence of hydrazine monohydrate. GO and GNs were characterized by X-ray photoelectron spectroscopy (XPS), Fourier transform infrared spectroscopy (FTIR), X-ray diffractions (XRD), Raman spectroscopy, Transmission electron microscopy (TEM), Atomic force microscopy (AFM), Optical microscopy (OM) and by electrical conductivity measurements. The result showed that electrical conductivity of GNs was significantly improved, from $4.2{\times}10^{-4}$ S/m for GO to 12 S/m for GNs, possibly due to the removal of oxygen-containing functional group during chemical reduction. In addition, the $NO_2$ gas sensing characteristics of GNs are also discussed.


  • 주제어

    Graphene .   Graphene oxide .   Gas sensing.  

  • 참고문헌 (44)

    1. Y. Zhu, S. Murali, W. Cai, X. Li, J.W. Suk, J.R. Potts and R.S. Ruoff, "Graphene and graphene oxide: Synthesis, properties, and applications", Adv. Mater. 22 (2010) 3906. 
    2. C.N.R. Rao, A.K. Sood, K.S. Subrahmanyam and A. Govindaraj, "Graphene: The new-two-demensional nanometerial", Angew. Chem. Int. Ed. 48 (2009) 7752 
    3. S. Capone, A. Forleo, L. Francioso, R. Rella, P. Siciliano, J. Spadavecchia, D.S. Presicceand and A.M. Taurino, "Solid-state gas sensors: state of the art and future activities", J. Optoelectron. Adv. Mater. 5 (2003) 1335. 
    4. K.S. Novoselov, A.K. Geim, S.V. Morozov, D. Jiang, Y. Zhang, S.V. Dubonos, I.V. Grigorieva and A.A. Firsov, "Electric field effect in atomically thin carbon films", Science 306 (2004) 666. 
    5. K.H. Choi, I.J. Yoo, H.S. Lee, K.H. Lee and D.C. Lim, "Fabrication of various carbon nanostructures by using different catalysts", J. Korean Crystal Growth and Crystal Technology 20 (2010) 133.     
    6. J.H. Kim, J.H. Hwang, T.Y. Lim and S.H. Kim, "Fabrication of functional nanoparticles by layer-by-layer selfassembly method", J. Korean Crystal Growth and Crystal Technology 19 (2009) 305. 
    7. R.H. Baughman, A.A. Zakhidov and W.A. de Heer, "Carbon nanotubes; The route toward applications", Science 297 (2002) 787. 
    8. M. Ferrari, "Cancer nanotechnology: Opportunities and challenges", Nat. Rev. Cancer 5 (2005) 161. 
    9. D.R. Kauffman and A. Star, "Carbon nanotube gas and vapor sensors", Angew. Chem., Int. Ed. 47 (2008) 6550 
    10. "Special issue on gas-sensing materials", MRS Bull. 24 (1999). 
    11. K.S. Novoselov, A.K. Geim, S.V. Morozov, D. Jiang, M.I. Katsnelson, I.V. Grigorieva, S.V. Dubonos and A.A. Firsov, "Two-dimensional gas of massless Dirac fermions in graphene", Nature 438 (2005) 197. 
    12. C. Berger, Z.M. Song, X.B. Li, X.S. Wu, N. Brown, C. Naud, D. Mayo, T.B. Li, J. Hass, A.N. Marchenkov, E.H. Conrad, P.N. First and W.A. de Heer, "Electronic confinement and coherence in patterned epitaxial graphene", Science 312 (2006) 1191. 
    13. Y. Shao, J. Wang, H. Wu, J. Liu, I.A. Aksay and Y. Lin, "Based electrochemical sensors and biosensors: A review", Electroanalysis 22 (2010) 1027. 
    14. Y.B. Zhang, J.P. Small, M.E.S. Amori and P. Kim, "Electric field modulation of galvanomagnetic properties of mesoscopic graphite", Phys. Rev. Lett. 94 (2005) 176803. 
    15. M.C. Lemme, T.J. Echtermeyer, M. Baus and H. Kurz, "A graphene field-effect device", IEEE Electron Device Lett. 28 (2007) 282. 
    16. F. Schedin, A.K. Geim, S.V. Morozov, E.W. Hill, P. Blake, M.I. Katsnelson and K.S. Novoselov, "Detection of individual gas molecules adsorbed on graphene", Nat. Mater. 6 (2007) 652. 
    17. R.S. Sundaram, C.G. Navarro, K. Balasubramanian, M. Burghard and K. Kern, "Electrochemical modification of graphene", Adv. Mater. 20 (2008) 3050. 
    18. P.K. Ang, W. Chen, A.T.S. Wee and K.P. Loh, "Solution-gated epitaxial graphene as pH sensor", J. Am. Chem. Soc. 130 (2008) 14392. 
    19. O. Leenaerts, B. Partoens and F.M. Peeters, "Adsorption of $H_{2}O$, $NH_{3}$, CO, $NO_{2}$, and NO on graphene: A first-principles study", Phy. Rev. B 77 (2008) 125416. 
    20. B. Huang, Z. Li, Z. Liu, G. Zhou, S. Hao, J. Wu, B.L. Gu and W. Duan, "Adsorption of gas molecules on graphene nanoribbons and its implication for nanoscale molecule sensor", J. Phys. Chem. C 112 (2008) 13442. 
    21. S. Peng and K. Cho, "Ab initio study of doped carbon nanotube sensors", Nano Lett. 3 (2003) 513. 
    22. C.S. Yeung, L.V. Liu and Y.A. Wang, "Adsorption of small gas molecules onto pt-doped single-walled carbon nanotubes", J. Phys. Chem. C 112 (2008) 7401. 
    23. M. Qazi, T. Vogt and G. Koley, "Trace gas detection using nanostructured graphite layers", Appl. Phy. Lett. 91 (2007) 233101. 
    24. I. Jung, D. Dikin, S. Park, W. Cai, S.L. Mielke and R.S. Ruoff, "Effect of water vapor on electrical properties of individual reduced graphene oxide sheets", J. Phys. Chem. C 112 (2008) 20264. 
    25. J.T. Robinson, F.K. Perkins, E.S. Snow, Z. Wei and P.E. Sheehan, "Reduced graphene oxide molecular sensors", Nano Lett. 8 (2008) 3137. 
    26. J.D. Fowler, M.J. Allen, V.C. Tung, Y. Yang, R.B. Kaner and B.H. Weiller, "Practical chemical sensors from chemically derived graphene", ACS Nano 3 (2009) 301. 
    27. W.S. Hummers and R.E. Offerman, "Preparation of graphitic oxide, J. Am. Chem. Soc. 80(6) (1958) 1339. 
    28. S. Stankovich, D.A. Dikin, R.D. Piner, K.A Kohlhaas, A. Kleinhammes, Y. Jia, Y. Wu, S.B.T. Nguyen and R.S. Ruoff, "Synsthesis of graphene-based nanosheets via chemical reduction of exfoliated", Carbon 45 (2007) 1558. 
    29. C. Hontorialucas, A.J. Lopezpeinado, J.D.D. Lopezgonzalez, M.L. Rojascervantes and R.M. Martinaranda, "Study of oxygen-containing groups in a series of graphite oxides: Physical and chemical characterization", Carbon 33 (1995) 1585. 
    30. C. Nethravathi and M. Rajamathi, "Chemically modified graphene sheets produced by the solvothermal reduction of colloidal dispersions of graphite oxide", Carbon 46 (2008) 1994. 
    31. A.C. Ferrari, J.C. Meyer, V. Scardaci, C. Casiraghi, M. Lazzeri, F. Mauri, S. Piscanec, D. Jiang, K.S. Novoselov and S. Roth, "Raman spectrum of graphene and graphene layers", Phys. Rev. Lett. 97 (2006) 187401. 
    32. J.I. Paredes, S. Villar-Rodil, P. Solis-Ferander, A. Martinez- Alonso and J.M.D. Tascon, "Atomic force and scanning tunneling microscopy imaging of graphene nanosheets derived from graphite oxide", Langmuir 30(10) (2009) 5957. 
    33. B.J. Jiang, C.G. Tian, L. Wang, Y.X. Xu, R.H. Wang, Y.J. Qiao, Y.G. Ma and H.G. Fu, "Facile fabrication of high quality graphene from expandable graphite: simultaneous exfoliation and reduction", Chem. Commun. 46 (2010) 4920. 
    34. M. Chouciar, P. Thordarson and J.A. Stride, "Gramscale production of graphene based on solvothermal synthesis and sonication", Nat. Nanotechnol. 4 (2009) 30. 
    35. G. Eda, G. Fanchini and M. Chhowalla, "Large-area ultrathin films of reduced graphene oxide as a transparent and flexible electronic material", Nat. Nanotechnol. 3 (2008) 270. 
    36. S. Park, J. An, R.D. Piner, I. Jung, D. Yang, A. Velamakanni, S.T. Nguyen and R.S. Ruoff", Aqueous suspension and characterization of chemically modified graphene sheets", Chem. Mater. 20 (2008) 6592. 
    37. D.C. Wei, Y.Q. Liu, Y. Yang, H.L. Zhang, L.P. Huang and G. Yu, "Synthesis of N-doped graphene by chemical vapor deposition and its electrical properties", Nano Lett. 9 (2009) 1752. 
    38. D.H. Lee, W.J. Lee and S.O. Kim, "Highly efficient vertical growth of wall-number-selected, N-doped carbon nanotube arrays", Nano Lett. 9 (2009) 1427. 
    39. C. Gomez-Navarro, R.T. Weitz, A.M. Bittner, M. Scolari, A. Mews, M. Burghard and K. Kern, "Electronic transport properties of individual chemically reduced graphene oxide sheets", Nano Lett. 11 (2007) 3499. 
    40. P.G. Ren, D.X. Yan, X. Ji, T. Chen and Z.M. Li, "Temperature dependence of graphene oxide reduced by hydrazine hydrate", Nanotechnology 22 (2011) 055705. 
    41. J. Moser, A. Verdaguer, D. Jimenez, A. Barreiro and A. Bachtold, "The enviroment of graphene probed by electrostatic force microscopy", Appl. Phys. Lett. 92 (2008) 123507. 
    42. G. Ko, J. Kim, J. Ahn, Y.M. Park and L. Kim, "Gaphene-based nitrogen dioxide gas sensors", Current Appl. Physics 10 (2010) 1002. 
    43. F. Yavari, Z. Chen, A.V. Thomas, W. Ren, H.M. Cheng and N. Koratkar, "High sensitivity gas detection using a macroscopic three-dimensional grephene foam network", Scientific Reports doi:10.1038/srep00166. 
    44. M. Penza, G. Gassano, R. Rossi, M. Alvisi, A. Rizzo, M.A. Signore, Th. Dikonimos, E. Serra and R. Giorgi, "Enhancement of sensitivity in gas chemiresistors based on carbon nanotube surface functionalized with noble metal (Au, Pt) nanoclusters", Appl. Phys. Lett. 90 (2007) 173123. 
  • 이 논문을 인용한 문헌 (1)

    1. Kim, Hee Jin ; Kim, Hyeungkeun ; Kim, Yena ; Lee, Woo Sung ; Yoon, Dae Ho ; Yang, Woo Seok 2013. "The study of thermal properties of graphene/Cu foam hybrid structures" 한국결정성장학회지 = Journal of the Korean crystal growth and crystal technology, 23(5): 235~240     

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