본문 바로가기
HOME> 논문 > 논문 검색상세

논문 상세정보

Journal of applied biological chemistry   v.61 no.2, 2018년, pp.191 - 194   KCI
본 등재정보는 저널의 등재정보를 참고하여 보여주는 베타서비스로 정확한 논문의 등재여부는 등재기관에 확인하시기 바랍니다.

수도작 작물의 과불소화합물 흡수이행성
Bioconcentration factor of perfluorochemicals for each aerial part of rice

최근형   (Chemical Safety Division, National Institute of Agricultural Sciences, RDA  ); 이득영   (Department of Agricultural Chemistry, Institute of Agriculture and Life Science (IALS), Gyeongsang National University  ); 배지연   (Department of Agricultural Chemistry, Institute of Agriculture and Life Science (IALS), Gyeongsang National University  ); 노진호   (Chemical Safety Division, National Institute of Agricultural Sciences, RDA  ); 문병철   (Chemical Safety Division, National Institute of Agricultural Sciences, RDA  ); 김진효   (Department of Agricultural Chemistry, Institute of Agriculture and Life Science (IALS), Gyeongsang National University  );
  • 초록

    국내 주요 식량작물인 벼에서의 잔류성 유기오염물질 잔류평가는 인체 위해성 평가에서 매우 중요하다. 본 연구에서는 과불소화합물 중 perfluorooctanoic acid (PFOA)와 perfluorooctane sulfonic acid (PFOS)의 잔류평가를 벼의 부위별 흡수이행성을 조사하여 수행하였다. 벼는 저농도 오염처리구( $1mg\;kg^{-1}$ )와 고농도 오염처리구( $5mg\;kg^{-1}$ )에서 재배 후 현미, 왕겨, 볏짚으로 나누어 잔류량을 조사하였고, 시험결과 현미의 과불소화합물 흡수이행성(0.002-0.006)이 다른 부위에 비해 가장 낮은 것으로 확인되었다. 잔류수준은 볏짚에서 가장 높게 나타났으며, 다음으로 왕겨와 현미 순이었고, 볏짚의 PFOA와 PFOS의 생물농축계수는 최대 1.474와 4.700으로 확인되었다.


    Perfluorooctanoic acid (PFOA) and perfluorooctane sulfonic acid (PFOS) are emerging pollutants in agricultural product, and the residual patterns and the uptake potentials were only studied on several crops, not on rice. The residue level and bioconcentration factor (BCF) of PFOA and PFOS were investigated on the low ( $1mg\;kg^{-1}$ ) and the high contaminated soil ( $5mg\;kg^{-1}$ ) groups. The residue levels in brown rice in the low group and in the high group were 0.002-0.004 and $0.008-0.030mg\;kg^{-1}$ of the each perfluorinated compounds (PFCs), and in the rice husk were $0.035-0.074mg\;kg^{-1}$ and $0.125-0.376mg\;kg^{-1}$ of the each PFCs, respectively. Furthermore, the residues in rice straw were the highest level in the all rice parts both in the groups. The PFOA and PFOS were reached to $3.723mg\;kg^{-1}$ and $7.641mg\;kg^{-1}$ , respectively, and the BCF (1.474 and 4.700) as well.


  • 주제어

    과불소화합물  .  . 생물농축계수  . 잔류  . 토양  .

  • 참고문헌 (19)

    1. Wang Z, Cousins IT, Scheringer M, Buck RC, Hungerbuhler K (2014) Global emission inventories for C4-C14 perfluoroalkyl carboxylic acid (PFCA) homologues from 1951 to 2030, Part I: production and emissions from quantifiable sources. Environ Int 70: 62-75 doi:10.1016/j.envint.2014.04.013 
    2. Zareitalabad P, Siemens J, Hamer M, Amelung W (2013) Perfluorooctanoic acid (PFOA) and perfluorooctanesulfonic acid (PFOS) in surface waters, sediments, soils and wastewater-A review on concentrations and distribution coefficients. Chemosphere 91: 725-732 doi:10.1016/j.chemosphere.2013.02.024 
    3. Arvaniti OS, Stasinakis AS (2015) Review on the occurrence, fate and removal of perfluorinated compounds during wastewater treatment. Sci Total Environ 524-525: 81-92 doi:10.1016/j.scitotenv.2015.04.023 
    4. Kim JH, Ok YS, Choi GH, Park BJ (2015) Residual perfluorochemicals in the biochar from sewage sludge. Chemosphere 134: 435-437 doi:10.1016/j.chemosphere.2015.05.012 
    5. Choi GH, Lee DY, Seo DC, Kim LS, Lim SJ, Ryu SH, Park BJ, Kim JH, Kim JH (2018a) Endosulfan Plant Uptake Suppression Effect on Char Amendment in Oriental Radish. Water Air Soil Pollut. 229: 24. doi.org/10.1007/s11270-017-3677-x 
    6. Heo JJ, Lee JW, Kim SK, Oh JE (2014) Foodstuff analyses show that seafood and water are major perfluoroalkyl acids (PFAAs) sources to humans in Korea. J Hazard Mater 279: 402-409 doi:10.1016/j.jhazmat.2014.07.004 
    7. Perez F, Llorca M, Kock-Schulmeyer M, Skrbic B, Oliveira LS, da Boit Martinello K, Al-Dhabi NA, Antic I, Farre M, Barcelo D (2014) Assessment of perfluoroalkyl substances in food items at global scale. Environ Res 135: 181-189 doi:10.1016/j.envres.2014.08.004 
    8. Post GB, Cohn PD, Cooper KR (2012) Perfluorooctanoic acid (PFOA), an emerging drinking water contaminant: a critical review of recent literature. Environ Res 116: 93-117 doi:10.1016/j.envres.2012.03.007 
    9. Clarke DB, Bailey VA, Routledge A, Lloyd AS, Hird S, Mortimer DN, Gem M (2010) Dietary intake estimate for perfluorooctanesulphonic acid (PFOS) and other perfluorocompounds (PFCs) in UK retail foods following determination using standard addition LC-MS/MS. Food Addit Contam Part A Chem Anal Control Expo Risk Assess 27: 530-545 doi:10.1080/19440040903476590 
    10. van Asselt ED, Kowalczyk J, van Eijkeren JCH, Zeilmaker MJ, Ehlers S, Furst P, Lahrssen-Wiederholt M, van der Fels-Klerx HJ (2013) Transfer of perfluorooctane sulfonic acid (PFOS) from contaminated feed to dairy milk. Food Chem 141: 1489-1495 doi:10.1016/j.foodchem.2013.04.035 
    11. Choi GH, Lee DY, Jeong DK, Kuppusamy S, Lee YB, Park BJ, Kim JH (2017) Perfluorooctanoic acid (PFOA) and perfluorooctanesulfonic acid (PFOS) concentrations in the South Korean agricultural environment: A national survey. J. Integr. Agric. 16: 1841-1851 
    12. Lam NH, Cho CR, Lee JS, Soh HY, Lee BC, Lee JA, Tatarozako N, Sasaki K, Iwabuchi K, Kannan K, Cho HS (2014) Perfluorinated alkyl substances in water, sediment, plankton and fish from Korean rivers and lakes: a nationwide survey. Sci Total Environ 491-492:154-162 doi:10.1016/j.scitotenv.2014.01.045 
    13. Kim HY, Kim SK, Kang DM, Hwang YS, Oh JE (2014) The relationships between sixteen perfluorinated compound concentrations in blood serum and food, and other parameters, in the general population of South Korea with proportionate stratified sampling method. Sci Total Environ 470-471: 1390-1400 doi:10.1016/j.scitotenv.2013.06.039 
    14. Blaine AC, Rich CD, Sedlacko EM, Hundal LS, Kumar K, Milis MA, Harris KM, Higgins CP (2014) Perfluoroalkyl acid distribution in various plant compartments of edible crops grown in biosolids-amended soils. Environ Sci Technol 48: 7858-7865 doi:10.1021/es500016s 
    15. Lechner M, Knapp H (2011) Carryover of perfluorooctanoic acid (PFOA) and perfluorooctane sulfonate (PFOS) from soil to plant and distribution to the different plant compartments studied in cultures of carrots (Daucus carota ssp. Sativus), potatoes (Solanum tuberosum), and cucumbers (Cucumis Sativus). J Agric Food Chem 59: 11011-11018 doi:10.1021/jf201355y 
    16. Zhao H, Guan Y, Zhang G, Zhang Z, Tan F, Quan X, Chen J (2013) Uptake of perfluorooctane sulfonate (PFOS) by wheat (Triticum aestivum L.) plant. Chemosphere 91: 139-144 doi:10.1016/j.chemosphere.2012.11.036 
    17. Choi GH, Choi DS, Hong SM, Kwon OK, Eun HS, Kim JH, Kim JH (2012) Investigation on Polychlorinated Dibenzo-p-dioxins, Polychlorinated Dibenzofurans and Dioxin-like Polychlorinated Biphenyls of Grains and Estimation of Dietary Intake for Korean. J Appl Biol Chem. 55: 253-261 
    18. Choi GH, Lee DY, Ryu SH, Park BJ, Moon BC, Kim JH (2018b) Investigation of the Bioconcentration Factor of Endosulfan for Rice from Soil. Korean J Pestic Sci 22: 25-28 
    19. Ballesteros-Gomez A, Rubio S, van Leeuwen S (2010) Tetrahydrofuranwater extraction, in-line clean-up and selective liquid chromatography/tandem mass spectrometry for the quantitation of perfluorinated compounds in food at the low picogram per gram level. J Chromatogr A 1217: 5913-5921 doi:10.1016/j.chroma.2010.07.032 

 활용도 분석

  • 상세보기

    amChart 영역
  • 원문보기

    amChart 영역

원문보기

무료다운로드
  • NDSL :
  • 한국응용생명화학회 : 저널
  • ScienceCentral : 저널
유료다운로드

유료 다운로드의 경우 해당 사이트의 정책에 따라 신규 회원가입, 로그인, 유료 구매 등이 필요할 수 있습니다. 해당 사이트에서 발생하는 귀하의 모든 정보활동은 NDSL의 서비스 정책과 무관합니다.

원문복사신청을 하시면, 일부 해외 인쇄학술지의 경우 외국학술지지원센터(FRIC)에서
무료 원문복사 서비스를 제공합니다.

NDSL에서는 해당 원문을 복사서비스하고 있습니다. 위의 원문복사신청 또는 장바구니 담기를 통하여 원문복사서비스 이용이 가능합니다.

이 논문과 함께 출판된 논문 + 더보기