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Journal of electrical engineering & technology v.13 no.6, 2018년, pp.2385 - 2391   SCIE
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Decomposition Properties of Trifluoroiodomethane under Discharges and Interruptions

Cai, Fan-Yi   (NARI Group Corp., State Grid Electric Power Research Institute  ); Tan, Dong-Xian   (Dept. of Electrical Engineering, Shanghai Jiao Tong University  ); Zhou, Bai-Jie   (NARI Group Corp., State Grid Electric Power Research Institute  ); Xue, Jian   (NARI Group Corp., State Grid Electric Power Research Institute  ); Xiao, Deng-Ming   (Dept. of Electrical Engineering, Shanghai Jiao Tong University  );
  • 초록

    This paper is devoted to detecting decomposition characteristics of Iodotrifluoromethane ( $CF_3I$ ) under alternating current (AC) discharges or load current interruptions. The decomposition products are measured utilizing chromatography-mass spectroscopy. It is found that less than 1% $CF_3I$ gas decomposed after several interruptions at load current of 200 A or hundred times of AC discharges. However, under interruptions at a current of 400 A, more than 95% $CF_3I$ gas decomposed into carbon tetrafluoride ( $CF_4$ ) and hexafluoroethane ( $C_2F_6$ ). The equilibrium compositions based on Gibbs free energy minimization of $CF_3I$ was calculated to explain the decomposition mechanism.


  • 주제어

    $CF_3I$ .   Decomposition products .   Interruption.  

  • 참고문헌 (25)

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