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ACS applied materials & interfaces v.9 no.2, 2017년, pp.1416 - 1425   SCI SCIE
본 등재정보는 저널의 등재정보를 참고하여 보여주는 베타서비스로 정확한 논문의 등재여부는 등재기관에 확인하시기 바랍니다.

Na2Ti3O7 Nanoplatelets and Nanosheets Derived from a Modified Exfoliation Process for Use as a High-Capacity Sodium-Ion Negative Electrode

Ko, Jesse S. (Department of Materials Science and Engineering, University of California, Los Angeles, Los Angeles, California 90095, ); Doan-Nguyen, Vicky V. T. (California NanoSystems Institute, University of California, Santa Barbara, Santa Barbara, California 93106, ); Kim, Hyung-Seok (Department of Materials Science and Engineering, University of California, Los Angeles, Los Angeles, California 90095, ); Muller, Guillaume A. (Department of Materials Science and Engineering, University of California, Los Angeles, Los Angeles, California 90095, ); Serino, Andrew C. (Department of Materials Science and Engineering, University of California, Los Angeles, Los Angeles, California 90095, ); Weiss, Paul S. (Department of Materials Science and Engineering, University of California, Los Angeles, Los Angeles, California 90095, ); Dunn, Bruce S. (Department of Materials Science and Engineering, University of California, Los Angeles, Los Angeles, California 90095, );
  • 초록  

    The increasing interest in Na-ion batteries (NIBs) can be traced to sodium abundance, its low cost compared to lithium, and its intercalation chemistry being similar to that of lithium. We report that the electrochemical properties of a promising negative electrode material, Na 2 Ti 3 O 7 , are improved by exfoliating its layered structure and forming 2D nanoscale morphologies, nanoplatelets, and nanosheets. Exfoliation of Na 2 Ti 3 O 7 was carried out by controlling the amount of proton exchange for Na + and then proceeding with the intercalation of larger cations such as methylammonium and propylammonium. An optimized mixture of nanoplatelets and nanosheets exhibited the best electrochemical performance in terms of high capacities in the range of 100–150 mA h g –1 at high rates with stable cycling over several hundred cycles. These properties far exceed those of the corresponding bulk material, which is characterized by slow charge-storage kinetics and poor long-term stability. The results reported in this study demonstrate that charge-storage processes directed at 2D morphologies of surfaces and few layers of sheets are an exciting direction for improving the energy and power density of electrode materials for NIBs. Graphic Abstract ACS Electronic Supporting Info


  • 주제어

    Na-ion battery .   2D materials .   anode .   nanomaterials .   electrochemistry .   high rate.  

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