Bromination of N-phenyloxypropyl-N'-ethyl-4,4'-bipyridium in cucurbituril molecular reactor
CB[n] (n=6-8) is a family of synthetic macrocyclic host molecules composed of n glycoluril units, which can be employed as molecular reactor. N-Phenyloxypropyl-N'-ethyl-4,4'-bipyridium (1) was designed to form a host-guest inclusion complex with CB[n] (n=6-8), subsequently, the bromination reaction of 1 and its corresponding inclusion complexes was investigated in this work. In the case of 1/CB, the folded including mode is quite helpful to acquire 1-bormination product completely through intramolecular charge transfer (ICT), and CB can provide a safe bromination environment for 1.
- 원문이 없습니다.
NDSL에서는 해당 원문을 복사서비스하고 있습니다. 위의 원문복사신청 또는 장바구니 담기를 통하여 원문복사서비스 이용이 가능합니다.
- 이 논문과 함께 출판된 논문 + 더보기