Platinum-nickel hydroxide nanocomposites for electrocatalytic reduction of water
Abstract Water electrolysis represents a promising solution for storage of renewable but intermittent electrical energy in hydrogen molecules. This technology is however challenged by the lack of efficient electrocatalysts for the hydrogen and oxygen evolution reactions. Here we report on the synthesis of platinum-nickel hydroxide nanocomposites and their electrocatalytic applications for water reduction. An in situ reduction strategy taking advantage of the Ni(II)/Ni(III) redox has been developed to enable and regulate the overgrowth of Pt nanocrystals on single-layer Ni(OH) 2 nanosheets. The obtained nanocomposites (denoted as Pt@2D-Ni(OH) 2 ) exhibit an improvement factor of 5 in catalytic activity and a reduction of up to 130mV in overpotential compared to Pt for the hydrogen evolution reaction (HER). A combination of electron microscopy/spectroscopy characterizations, electrochemical studies and density function theory calculations was employed to uncover the structures of the metal-hydroxide interface and understand the mechanisms of catalytic enhancement. Highlights Developed the overgrowth of Pt nanocrystals on single-layer Ni(OH) 2 nanosheets Demonstrated 5-times improvement in electrocatalytic activity for water reduction Revealed a Pt-Ni-OH type of interface as the catalytically active sites Depicted the reaction pathway of water reduction at the Pt-Ni-OH interface Graphical abstract [DISPLAY OMISSION]
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