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Journal of electroanalytical chemistry v.785, 2017년, pp.180 - 189   SCI SCIE
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Electrochemical oxidation of phenolic wastewaters using a batch-stirred reactor with NaCl electrolyte and Ti/RuO2 anodes

Fajardo, Ana S. (CIEPQPF – ); Seca, Helga F. (Chemical Process Engineering and Forest Products Research Centre, GERST – ); Martins, Rui C. (Group on Environment, Reaction, Separation and Thermodynamics, Department of Chemical Engineering, Faculty of Sciences and Technology, University of Coimbra, Pólo II, Rua Sílvio Lima, 3030-790 Coimbra, Portugal ); Corceiro, Vanessa N. (CIEPQPF – ); Freitas, Inês F. (Chemical Process Engineering and Forest Products Research Centre, GERST – ); Quinta-Ferreira, M. Emília (Group on Environment, Reaction, Separation and Thermodynamics, Department of Chemical Engineering, Faculty of Sciences and Technology, University of Coimbra, Pólo II, Rua Sílvio Lima, 3030-790 Coimbra, Portugal ); Quinta-Ferreira, Rosa M. (CIEPQPF – );
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    Abstract An electrochemical oxidation (EO) process with Ti/RuO 2 anodes was applied to treat phenolic wastewaters. In order to optimise the system, different operating conditions were tested. The nature of the electrolyte and the applied current density greatly affected the process, while the concentration of the electrolyte as well as the initial pH had a sparingly impact. The optimum operating conditions attained, 10gL −1 of NaCl, 119mAcm −2 and initial pH3.4, allowed the complete removal of the total phenolic content (TPh) and chemical oxygen demand (COD) when applied to a simulated phenolic mixture. SEM analysis revealed no morphological differences on the surface of the anode before and after it being used in EO. Neuronal studies were performed to verify the impact of the synthetic phenolic effluent, before and after the EO treatment, in the formation of neuronal reactive oxygen species (ROS). The treated effluent had a milder effect, compared to the raw one, but neuronal activity became enhanced after its removal. Regarding the depuration of an undiluted real olive mill wastewater (OMW) under the optimised parameters, the treatment achieved 100% of TPh removal and 17.2% of COD removal. Thus, the EO can be considered a satisfactory pre-treatment process to real wastewaters, since all phenolic content can be removed in 180min. Highlights Use of Ti/RuO 2 anodes to depurate phenolic wastewaters. NaCl electrolyte is preferred to Na 2 SO 4 . No morphological differences were detected on the surface of the anode after treatment. Evaluation of the effect of the treatment on neuronal activity. EO using Ti/RuO 2 anodes is a satisfactory pre-treatment to undiluted real wastewaters.


  • 주제어

    Electrochemical oxidation .   Phenolic compound .   Olive mill wastewater .   Ti/RuO2 anode .   NaCl .   ROS .   H2DCFDA .   Neuronal toxicity.  

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