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Journal of electroanalytical chemistry v.785, 2017년, pp.265 - 278   SCI SCIE
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Aryldiazonium salt derived mixed organic layers: From surface chemistry to their applications

Jiang, Cheng (School of Chemistry, Australian Centre for NanoMedicine and ARC Centre of Excellence in Convergent Bio-Nano Science and Technology, The University of New South Wales, Sydney, NSW 2052, Australia ); Moraes Silva, Saimon (School of Chemistry, Australian Centre for NanoMedicine and ARC Centre of Excellence in Convergent Bio-Nano Science and Technology, The University of New South Wales, Sydney, NSW 2052, Australia ); Fan, Sanjun (School of Chemistry, Australian Centre for NanoMedicine and ARC Centre of Excellence in Convergent Bio-Nano Science and Technology, The University of New South Wales, Sydney, NSW 2052, Australia ); Wu, Yanfang (School of Chemistry, Australian Centre for NanoMedicine and ARC Centre of Excellence in Convergent Bio-Nano Science and Technology, The University of New South Wales, Sydney, NSW 2052, Australia ); Alam, Muhammad Tanzirul (School of Chemistry, Australian Centre for NanoMedicine and ARC Centre of Excellence in Convergent Bio-Nano Science and Technology, The University of New South Wales, Sydney, NSW 2052, Australia ); Liu, Guozhen (Key Laboratory ); Justin Gooding, J. ( );
  • 초록  

    Abstract Formation of multicomponent layers via electrografting of aryldiazonium salts has been recognized by materials scientists and electrochemists as a powerful tool due to their high capability for covalent surface modification with multiple functionalities. The past decades have seen significant progress in fabrication and application of surfaces decorated with layers containing more than one component, so called mixed layers. This progress is based on advances in the understanding of aryldiazonium salt-based electrochemistry and their surface chemistry properties. In this critical review, we summarize the different strategies for controlling formation of the mixed layers, especially with respect to surface composition, spatial distribution and surface morphology whereupon the focus shifts to the diverse range of applications in which mixed layers are employed. The limitations of existing strategies and perspective opportunities will also be presented.


  • 주제어

    Mixed layers .   Aryldiazonium salts .   Electrografting .   Surface chemistry .   Sensing applications.  

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