본문 바로가기
HOME> 논문 > 논문 검색상세

논문 상세정보

Review—Manganese Dissolution from Spinel Cathode: Few Unanswered Questions

Bhandari, Arihant Bhattacharya, Jishnu
  • 초록  

    The choice of cathode material critically influences the performance, cost and energy density in a Li ion battery. LiMn 2 O 4 (LMO) cathode is an attractive cathode material because of its high rate capability, low cost, safety and non-toxicity. However, low cycle life or capacity fading with cycling is a big hurdle in the practical application of LMO cathodes. The dominant cause of the capacity fading, Mn dissolution from LMO, is still a challenge to overcome. In this review, we attempt to emphasize the loopholes in the understanding related to the Mn dissolution phenomenon in LMO cathodes in the presence of both aqueous and non-aqueous electrolytes. The underlying mechanism behind the dissolution process is often explained with the help of ionic charge disproportionation argument. Nevertheless, there are experimental and theoretical evidence in the literature to counter the simplistic view of dissolution due to charge disproportionation. Moreover, the correlation between the metal dissolution and the capacity fading is not causally established yet in the literature which hinders the formulation for a systematic strategy to prevent the capacity loss. In the current article we discuss all the relevant investigations related to the understanding of the cause, effect and prevention strategies of Mn-dissolution. We attempt to point out the gaps and contradictions in the literature and motivate further targeted studies in this seminally important material for better Li-ion batteries having higher rate capability and capacity retention.


  • 주제어

    cathode .   Li ion battery .   LiMn2O4 .   Mn disproportionation .   Mn dissolution .   spinel.  

 활용도 분석

  • 상세보기

    amChart 영역
  • 원문보기

    amChart 영역

원문보기

무료다운로드
  • 원문이 없습니다.
유료다운로드

유료 다운로드의 경우 해당 사이트의 정책에 따라 신규 회원가입, 로그인, 유료 구매 등이 필요할 수 있습니다. 해당 사이트에서 발생하는 귀하의 모든 정보활동은 NDSL의 서비스 정책과 무관합니다.

원문복사신청을 하시면, 일부 해외 인쇄학술지의 경우 외국학술지지원센터(FRIC)에서
무료 원문복사 서비스를 제공합니다.

NDSL에서는 해당 원문을 복사서비스하고 있습니다. 위의 원문복사신청 또는 장바구니 담기를 통하여 원문복사서비스 이용이 가능합니다.

이 논문과 함께 출판된 논문 + 더보기