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Journal of colloid and interface science v.512, 2018년, pp.844 - 852   SCI SCIE
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Facile synthesis of ultrafine cobalt oxides embedded into N-doped carbon with superior activity in hydrogenation of 4-nitrophenol

Zhang, Xiuling    (Key Laboratory of Coordination Chemistry and Functional Materials in Universities of Shandong, College of Chemistry and Chemical Engineering, De Zhou University, De Zhou 253023, PR China   ); Wang, Na    (College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao 266000, PR China   ); Geng, Longlong    (Key Laboratory of Coordination Chemistry and Functional Materials in Universities of Shandong, College of Chemistry and Chemical Engineering, De Zhou University, De Zhou 253023, PR China   ); Fu, Junna    (College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao 266000, PR China   ); Hu, Hui    (Key Laboratory of Coordination Chemistry and Functional Materials in Universities of Shandong, College of Chemistry and Chemical Engineering, De Zhou University, De Zhou 253023, PR China   ); Zhang, Dashuai    (Key Laboratory of Coordination Chemistry and Functional Materials in Universities of Shandong, College of Chemistry and Chemical Engineering, De Zhou University, De Zhou 253023, PR China   ); Zhu, Baoyong    (Key Laboratory of Coordination C  ); Carozza, Jesse   Han, Haixiang  
  • 초록  

    Abstract Design and synthesis of low-cost catalysts with high activity and stability for hydrogenation reactions is an important research area of applied catalysis. In this work, we present a kind of ultrafine cobalt oxides encapsulated by N-doped carbon (donated as CoO x /CN) as efficient catalysts for hydrogenation of 4-nitrophenol (4-NP) process. The CoO x /CN was fabricated through a pyrolysis strategy using an N-containing metal-organic framework (Co-MOF) as precursor followed by a fine thermal-treatment. With an optimized pyrolysis temperature of 500 °C, the CoO x species present as ultrafine particles highly dispersed in the obtained catalyst (CoO x /CN-500). CoO x /CN-500 exhibits excellent activity and stability in hydrogenation of 4-NP at ambient conditions. The activity is much higher than that of not only bulk cobalt oxides, but also carbon supported CoO x catalysts. It could be used for more than 8 times without obvious fading in activity. In addition, the concrete role of Co-MOF precursor and pyrolysis condition in the catalyst design was investigated in detail. The interaction between organic ligands and Co ions and the confinement of the crystalline structure of Co-MOF could restrain the aggregation of Co ions during pyrolysis and lead to high dispersion of ultrafine CoO x species. Meanwhile, the N-containing ligands could be transformed into doped N species (pyridinic and pyrrolic N), endowing the CoO x species with high electron density and promoting the formation of active sites for the hydrogenation reaction. Graphical abstract Ultrafine cobalt oxides embedded into N-doped carbon (CoO x /CN), synthesized via a MOF pyrolysis route, exhibit high catalytic activity and stability in hydrogenation of 4-nitrophenol at ambient conditions. [DISPLAY OMISSION]


  • 주제어

    Cobalt oxides .   Metal-organic frameworks .   N-doped carbon .   Hydrogenation reaction.  

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