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Journal of colloid and interface science v.512, 2018년, pp.701 - 712   SCI SCIE
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Cu(I)/Cu(II) mixed-valence surface complexes of S-[(2-hydroxyamino)-2-oxoethyl]-N,N-dibutyldithiocarbamate: Hydrophobic mechanism to malachite flotation

Liu, Sheng    (School of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China   ); Zhong, Hong    (School of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China   ); Liu, Guangyi    (School of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China   ); Xu, Zhenghe    (Department of Chemical and Materials Engineering, University of Alberta, Edmonton, Alberta T6G 2V4, Canada  );
  • 초록  

    Abstract Hypothesis Hydroxamate and sulfhydryl surfactants are effective collectors for flotation of copper minerals. The combination application of hydroxamate and sulfhydryl collectors has been proved to be an effective approach for improving the flotation recovery of non-sulfide copper minerals. A surfactant owing both hydroxamate and dithiocarbamate groups might exhibit strong affinity to non-sulfide copper minerals through double sites adsorption, rendering an enhanced hydrophobization to non-sulfide copper minerals flotation. Experiments The flotation performance of S -[(2-hydroxyamino)-2-oxoethyl]- N , N -dibutyldithiocarbamate (HABTC) to malachite, calcite and quartz were first evaluated through systematic micro-flotation experiments. HABTC's hydrophobic mechanism to malachite was further investigated and analyzed by zeta potential, Fourier transform infrared spectroscopy (FTIR), time-of-flight secondary ion mass spectrometry (ToF-SIMS) and X-ray photoelectron spectroscopy (XPS). Findings The micro-flotation results demonstrated HABTC was an excellent collector for malachite flotation and exhibited favorable selectivity for flotation separation of malachite from quartz or calcite under pH 8.5–10.3. Zeta potential and FTIR implied that HABTC might bond with the surface copper atoms of malachite, with releasing the H + ions of its hydroxamate group into pulp. ToF-SIMS provided clear evidences that the Cu-hydroxamate and Cu-dithiocarbamate groups were formed on malachite surfaces after HABTC adsorption. XPS revealed that Cu(I)/Cu(II) mixed-valence surface complexes of HABTC anchored on malachite through formation of Cu(I)S and Cu(II)O bonds, accompanying with reduction of partial surface Cu(II) to Cu(I). The Cu(I)/Cu(II) mixed-valence double chelating character and “chair”-shape N , N -dibutyldithiocarbamate hydrophobic group, resulting in an enhanced affinity and hydrophobization of HABTC to malachite flotation. Graphical abstract The hydrophobic mechanism of S -[(2-hydroxyamino)-2-oxoethyl]- N , N -dibutyl -dithiocarbamate (HABTC) to malachite (Cu 2 CO 3 (OH) 2 ). [DISPLAY OMISSION]


  • 주제어

    S-[(2-hydroxyamino)-2-oxoethyl]-N,N-dibutyldithiocarbamate .   Malachite .   Flotation mechanism .   Cu(I)/Cu(II) mixed-valence surface complexes .   ToF-SIMS.  

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