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Applied surface science v.433, 2018년, pp.1175 - 1183   SCI SCIE
본 등재정보는 저널의 등재정보를 참고하여 보여주는 베타서비스로 정확한 논문의 등재여부는 등재기관에 확인하시기 바랍니다.

Mechanistic insight into the enhanced photocatalytic activity of single-atom Pt, Pd or Au-embedded g-C3N4

Tong, Tong (Corresponding author. ) ; Zhu, Bicheng ; Jiang, Chuanjia ; Cheng, Bei ; Yu, Jiaguo ;
  • 초록  

    Abstract Single atoms of platinum (Pt), palladium (Pd) or gold (Au) trapped by two-dimensional graphitic carbon nitride (g-C 3 N 4 ) exhibit superior photocatalytic performance. However, the underlying mechanism of single-atom noble metal/g-C 3 N 4 photocatalytic system is still unclear. Herein, the structural, electronic and optical properties of single-atom Pt, Pd and Au loaded on bilayer g-C 3 N 4 (BL-g-C 3 N 4 ) substrate were investigated by density functional theory (DFT) simulations. The results indicate that single-atom Pt/Pd/Au loading can significantly narrow the band gap of g-C 3 N 4 and thus increase its light absorption in the visible-light region. Rather than being adsorbed on the surface, Pt and Pd atoms tend to be embedded into g-C 3 N 4 interlayer and act as bridges to facilitate the interlayer charge carrier transfer due to the effects of conduction band offset. In particular, an internal electric field is generated in Pt/BL-g-C 3 N 4 , which is further beneficial for separating charge carrier of photoexcited g-C 3 N 4 . By contrast, Au can only be adsorbed on the g-C 3 N 4 surface (in the six-fold cavity) and deliver a limited amount of charge carrier excited in the N-conjugated aromatic pore of g-C 3 N 4 surface. Our finding is conducive to understanding the interactive relationship between single-atom noble metal co-catalysts and g-C 3 N 4 and to the design of high-efficiency photocatalyst. Highlights Stable adsorption sites of single Pt, Pd and Au atoms on g-C 3 N 4 are determined. Single-atom (Pt/Pd/Au)/g-C 3 N 4 shows high charge carrier separation efficiency. Loading of single-atom Pt/Pd/Au in g-C 3 N 4 exhibits superior optical absorption. Single Pt and Pd atoms as bridge to facilitate g-C 3 N 4 interlayer charge transfer. Graphical abstract [DISPLAY OMISSION]


  • 주제어

    Graphitic carbon nitride .   Noble metal .   Single atom .   Density functional theory .   Photocatalysis .   Interlayer charge carrier transfer.  

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