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International journal of greenhouse gas control v.71, 2018년, pp.62 - 73   SCI SCIE
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Experimental study of gravitational mixing of supercritical CO2

Newell, Dennis L. (Department of Geology, Utah State University, Logan, UT 84322, United States ) ; Carey, J. William (Earth & Environmental Sciences, Los Alamos National Laboratory, Los Alamos, NM 87545, United States ) ; Backhaus, Scott N. (Materials Physics and Applications, Los Alamos National Laboratory, Los Alamos, NM 87545, United States ) ; Lichtner, Peter (OFM Research, Redmond, WA 98053, United States ) ;
  • 초록  

    Abstract CO 2 injection into saline aquifers for sequestration will initially result in buoyant supercritical (sc)CO 2 trapped beneath the caprock seal. During this period, there is risk of CO 2 migration out of the reservoir along wellbore defects or fracture zones. Dissolution of the scCO 2 plume into brine results in solubility trapping and reduces this risk, but based on diffusion alone, this mechanism could take thousands of years. Gravitational (density-induced) mixing of CO 2 -saturated brine is shown to significantly accelerate this process in computational studies, but few experimental efforts have confirmed the phenomenon. Here, constant-pressure, 3-dimensional bench-scale experiments used the mass of added water to quantify the mass transfer of scCO 2 into water-saturated porous media at 40–90 °C and 20 MPa, with Rayleigh numbers from 2093 to 16256. Experiments exhibit a period of 7–35X enhancement in mass transfer rates over diffusion, interpreted as gravitational mixing. Convective CO 2 flux ranges from 1.6 × 10 −2 to 4.8 × 10 −3 mol s −1 m −2 in the experiments. Results are used to benchmark a computational model using PFLOTRAN. Experiments show an early diffusive onset period that is shorter with rates much higher than predicted by models and observed in analog experiments. Both experiments and models show convective mixing periods and similar overall rates of CO 2 mass transfer. Highlights 3-D high-pressure experiments quantify the mass transfer of supercritical CO 2 into water-saturated porous media. Enhanced CO 2 mass-transfer to water via gravitational mixing experimentally measured at a range of reservoir conditions. Experimental results benchmark PFLOTRAN model simulations of density driven supercritical CO 2 –brine mixing.


  • 주제어

    Convective CO2 mixing .   Supercritical CO2-water experiments .   CO2 sequestration .   PFLOTRAN.  

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